Electrochemically Induced Intermolecular Cross-Dehydrogenative C–O Coupling of β-Diketones and β-Ketoesters with Carboxylic Acids
Тип публикации: Journal Article
Дата публикации: 2019-01-08
scimago Q2
wos Q1
БС1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
30618255
Organic Chemistry
Краткое описание
The electrochemically induced cross-dehydrogenative C-O coupling of β-diketones and β-ketoesters (C-H reagents) with carboxylic acids (O-H reagents) was developed. An important feature of this reaction lies in the selective formation of intermolecular C-O coupling products in high yields, up to 92%, using DMSO as a solvent with a broad substrate scope in an undivided cell equipped with carbon and platinum electrodes at high current density. Electric current acts as a stoichiometric oxidant.
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Bityukov O. V. et al. Electrochemically Induced Intermolecular Cross-Dehydrogenative C–O Coupling of β-Diketones and β-Ketoesters with Carboxylic Acids // Journal of Organic Chemistry. 2019. Vol. 84. No. 3. pp. 1448-1460.
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Bityukov O. V., Matveeva O. K., Vil’ V. A., Kokorekin V. A., Nikishin G. I., Terent'ev A. O. Electrochemically Induced Intermolecular Cross-Dehydrogenative C–O Coupling of β-Diketones and β-Ketoesters with Carboxylic Acids // Journal of Organic Chemistry. 2019. Vol. 84. No. 3. pp. 1448-1460.
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TY - JOUR
DO - 10.1021/acs.joc.8b02791
UR - https://pubs.acs.org/doi/10.1021/acs.joc.8b02791
TI - Electrochemically Induced Intermolecular Cross-Dehydrogenative C–O Coupling of β-Diketones and β-Ketoesters with Carboxylic Acids
T2 - Journal of Organic Chemistry
AU - Bityukov, Oleg V
AU - Matveeva, Olesya K
AU - Vil’, Vera A.
AU - Kokorekin, Vladimir A
AU - Nikishin, Gennady I.
AU - Terent'ev, Alexander O.
PY - 2019
DA - 2019/01/08
PB - American Chemical Society (ACS)
SP - 1448-1460
IS - 3
VL - 84
PMID - 30618255
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2019_Bityukov,
author = {Oleg V Bityukov and Olesya K Matveeva and Vera A. Vil’ and Vladimir A Kokorekin and Gennady I. Nikishin and Alexander O. Terent'ev},
title = {Electrochemically Induced Intermolecular Cross-Dehydrogenative C–O Coupling of β-Diketones and β-Ketoesters with Carboxylic Acids},
journal = {Journal of Organic Chemistry},
year = {2019},
volume = {84},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://pubs.acs.org/doi/10.1021/acs.joc.8b02791},
number = {3},
pages = {1448--1460},
doi = {10.1021/acs.joc.8b02791}
}
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MLA
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Bityukov, Oleg V., et al. “Electrochemically Induced Intermolecular Cross-Dehydrogenative C–O Coupling of β-Diketones and β-Ketoesters with Carboxylic Acids.” Journal of Organic Chemistry, vol. 84, no. 3, Jan. 2019, pp. 1448-1460. https://pubs.acs.org/doi/10.1021/acs.joc.8b02791.