Journal of Organic Chemistry

, volume 84 , issue 20 , pages 12746-12754

C–H Functionalizations by Palladium Carboxylates: The Acid Effect

JIŘÍ Váňa ¹

Jan Bartáček ¹

Jiří Hanusek ¹

Jana Roithová ²

Miloš Sedlák ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 53210 Pardubice, Czech Republic |

Department for Spectroscopy and Catalysis, Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands |

Publication type: Journal Article

Publication date: 2019-03-29

American Chemical Society (ACS)

Journal of Organic Chemistry

scimago Q2

wos Q1

SJR: 0.737

CiteScore: 6.1

Impact factor: 3.6

ISSN: 00223263, 15206904

DOI: 10.1021/acs.joc.9b00462

Copy DOI

PubMed ID: 30922054

Organic Chemistry

Abstract

Finding optimal reaction conditions is usually complex, requires many experiments, and is therefore demanding in terms of human, financial, and environmental resources. This work provides a simple workflow for easier design of popular palladium-catalyzed C-H functionalization reactions, where the active palladium catalysts contain carboxylate ligands. The key factor for optimizing reaction conditions is to find a balance between two opposing effects of the carboxylic acid in the reaction mixture: generation of more reactive palladium catalyst versus deactivation of a substrate by its protonation.

Found

2 citations

Yakushev Ilya

🥼

PhD in Chemistry

102 publications, 851 citations

h-index: 18

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Research interests

Interaction of X-ray, synchrotron radiation and neutrons with condensed matter

X-ray diffraction (XRD)

2 citations

Popova Anna

PhD in Chemistry

14 publications, 38 citations

h-index: 4

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Russian State Agrarian University - Moscow Timiryazev Agricultural Academy

Gas chromatography (GS)

Graphene

Graphene oxide

Heterogeneous catalysis

Synthesis of metal complexes

1 citation

Churakov Andrei

PhD in Chemistry

555 publications, 7 054 citations, 14 reviews

h-index: 38

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

1 citation

Dorovatovskii Pavel

343 publications, 4 064 citations

h-index: 28

National Research Centre "Kurchatov Institute"

1 citation

Budnikova Yulia

DSc in Chemistry, professor

260 publications, 4 537 citations, 54 reviews

h-index: 34

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

C-H functionalization

Catalysis

Charge transfer

Chemistry of organoelement compounds

1 citation

Balakina Marina

103 publications, 1 026 citations, 20 reviews

h-index: 18

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

1 citation

Maksimova Anna

8 publications, 3 citations

h-index: 1

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Mendeleev University of Chemical Technology of Russia

Research interests

Coordination Chemistry

1 citation

Ogarkova Nadezhda

6 publications, 13 citations

h-index: 2

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Peoples' Friendship University of Russia

1 citation

Panina Maria

4 publications, 6 citations

h-index: 2

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

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GOST |

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GOST Copy

Váňa J. et al. C–H Functionalizations by Palladium Carboxylates: The Acid Effect // Journal of Organic Chemistry. 2019. Vol. 84. No. 20. pp. 12746-12754.

GOST all authors (up to 50) Copy

Váňa J., Bartáček J., Hanusek J., Roithová J., Sedlák M. C–H Functionalizations by Palladium Carboxylates: The Acid Effect // Journal of Organic Chemistry. 2019. Vol. 84. No. 20. pp. 12746-12754.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.joc.9b00462

UR - https://doi.org/10.1021/acs.joc.9b00462

TI - C–H Functionalizations by Palladium Carboxylates: The Acid Effect

T2 - Journal of Organic Chemistry

AU - Váňa, JIŘÍ

AU - Bartáček, Jan

AU - Hanusek, Jiří

AU - Roithová, Jana

AU - Sedlák, Miloš

PY - 2019

DA - 2019/03/29

PB - American Chemical Society (ACS)

SP - 12746-12754

IS - 20

VL - 84

PMID - 30922054

SN - 0022-3263

SN - 1520-6904

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2019_Váňa,

author = {JIŘÍ Váňa and Jan Bartáček and Jiří Hanusek and Jana Roithová and Miloš Sedlák},

title = {C–H Functionalizations by Palladium Carboxylates: The Acid Effect},

journal = {Journal of Organic Chemistry},

year = {2019},

volume = {84},

publisher = {American Chemical Society (ACS)},

month = {mar},

url = {https://doi.org/10.1021/acs.joc.9b00462},

number = {20},

pages = {12746--12754},

doi = {10.1021/acs.joc.9b00462}

}

MLA

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MLA Copy

Váňa, JIŘÍ, et al. “C–H Functionalizations by Palladium Carboxylates: The Acid Effect.” Journal of Organic Chemistry, vol. 84, no. 20, Mar. 2019, pp. 12746-12754. https://doi.org/10.1021/acs.joc.9b00462.

Publisher

American Chemical Society (ACS)

Journal

Journal of Organic Chemistry

scimago Q2

wos Q1

SJR

0.737

CiteScore

6.1

Impact factor

3.6

ISSN

00223263 (Print)

15206904 (Electronic)