volume 84 issue 14 pages 9282-9296

Synthesis of Diiodinated All-Carbon 3,3′-Diphenyl-1,1′-spirobiindene Derivatives via Cascade Enyne Cyclization and Electrophilic Aromatic Substitution

Publication typeJournal Article
Publication date2019-07-01
scimago Q2
wos Q1
SJR0.737
CiteScore6.1
Impact factor3.6
ISSN00223263, 15206904
Organic Chemistry
Abstract
A synthetic method for the construction of diiodinated all-carbon spirobiindene derivatives has been developed from the reaction of propargyl alcohol-tethered alkylidenecyclopropanes with iodine. The reaction proceeded through an iodination-initiated cascade intramolecular enyne cyclization and electrophilic aromatic substitution reaction process in 1,2-dichloroethane upon heating, giving desired spirocyclic products in moderate to excellent yields. Further transformation of the obtained products has also been presented.
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GOST Copy
Li Q. et al. Synthesis of Diiodinated All-Carbon 3,3′-Diphenyl-1,1′-spirobiindene Derivatives via Cascade Enyne Cyclization and Electrophilic Aromatic Substitution // Journal of Organic Chemistry. 2019. Vol. 84. No. 14. pp. 9282-9296.
GOST all authors (up to 50) Copy
Li Q., Yu L., Wei Yin 尹., Shi M. Synthesis of Diiodinated All-Carbon 3,3′-Diphenyl-1,1′-spirobiindene Derivatives via Cascade Enyne Cyclization and Electrophilic Aromatic Substitution // Journal of Organic Chemistry. 2019. Vol. 84. No. 14. pp. 9282-9296.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.joc.9b01418
UR - https://doi.org/10.1021/acs.joc.9b01418
TI - Synthesis of Diiodinated All-Carbon 3,3′-Diphenyl-1,1′-spirobiindene Derivatives via Cascade Enyne Cyclization and Electrophilic Aromatic Substitution
T2 - Journal of Organic Chemistry
AU - Li, Quanzhe
AU - Yu, Liuzhu
AU - Wei Yin, 尹维
AU - Shi, Min
PY - 2019
DA - 2019/07/01
PB - American Chemical Society (ACS)
SP - 9282-9296
IS - 14
VL - 84
PMID - 31257888
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Li,
author = {Quanzhe Li and Liuzhu Yu and 尹维 Wei Yin and Min Shi},
title = {Synthesis of Diiodinated All-Carbon 3,3′-Diphenyl-1,1′-spirobiindene Derivatives via Cascade Enyne Cyclization and Electrophilic Aromatic Substitution},
journal = {Journal of Organic Chemistry},
year = {2019},
volume = {84},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.joc.9b01418},
number = {14},
pages = {9282--9296},
doi = {10.1021/acs.joc.9b01418}
}
MLA
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MLA Copy
Li, Quanzhe, et al. “Synthesis of Diiodinated All-Carbon 3,3′-Diphenyl-1,1′-spirobiindene Derivatives via Cascade Enyne Cyclization and Electrophilic Aromatic Substitution.” Journal of Organic Chemistry, vol. 84, no. 14, Jul. 2019, pp. 9282-9296. https://doi.org/10.1021/acs.joc.9b01418.