BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions
César Ray
1
,
Christopher Schad
1
,
Andres Garcia Sampedro
1
,
Beatriz L. Maroto
1
,
Jorge Bañuelos
2
,
Teresa Arbeloa
2
,
Inmaculada García-Moreno
3
,
Cassie Villafuerte
4
,
Gilles Muller
4
,
Santiago de la Moya
1
2
Departamento de Quı́mica Fı́sica, Facultad de Ciencia y Tecnologı́a, Universidad del Paı́s Vasco-EHU, 48080 Bilbao, Spain
|
Publication type: Journal Article
Publication date: 2020-03-06
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
32138513
Organic Chemistry
Abstract
A general and straightforward method for the synthesis of COO-BODIPYs from F-BODIPYs and carboxylic acids is established. The method is based on the use of boron trichloride to activate the involved substitution of fluorine, which leads to high yields through rapid reactions under soft conditions. This mild method opens the way to unprecedented laser dyes with outstanding efficiencies and photostabilities, which are difficult to obtain by the current methods.
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Total citations:
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Citations from 2024:
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GOST
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Ray C. et al. BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions // Journal of Organic Chemistry. 2020. Vol. 85. No. 7. pp. 4594-4601.
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Ray C., Schad C., Garcia Sampedro A., Maroto B. L., Bañuelos J., Arbeloa T., García-Moreno I., Villafuerte C., Muller G., de la Moya S. BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions // Journal of Organic Chemistry. 2020. Vol. 85. No. 7. pp. 4594-4601.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.joc.9b03059
UR - https://doi.org/10.1021/acs.joc.9b03059
TI - BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions
T2 - Journal of Organic Chemistry
AU - Ray, César
AU - Schad, Christopher
AU - Garcia Sampedro, Andres
AU - Maroto, Beatriz L.
AU - Bañuelos, Jorge
AU - Arbeloa, Teresa
AU - García-Moreno, Inmaculada
AU - Villafuerte, Cassie
AU - Muller, Gilles
AU - de la Moya, Santiago
PY - 2020
DA - 2020/03/06
PB - American Chemical Society (ACS)
SP - 4594-4601
IS - 7
VL - 85
PMID - 32138513
SN - 0022-3263
SN - 1520-6904
ER -
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BibTex (up to 50 authors)
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@article{2020_Ray,
author = {César Ray and Christopher Schad and Andres Garcia Sampedro and Beatriz L. Maroto and Jorge Bañuelos and Teresa Arbeloa and Inmaculada García-Moreno and Cassie Villafuerte and Gilles Muller and Santiago de la Moya},
title = {BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions},
journal = {Journal of Organic Chemistry},
year = {2020},
volume = {85},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.joc.9b03059},
number = {7},
pages = {4594--4601},
doi = {10.1021/acs.joc.9b03059}
}
Cite this
MLA
Copy
Ray, César, et al. “BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions.” Journal of Organic Chemistry, vol. 85, no. 7, Mar. 2020, pp. 4594-4601. https://doi.org/10.1021/acs.joc.9b03059.