volume 123 issue 21 pages 4575-4580

Interplay of Intra- and Intermolecular Interactions in Solid Iodine at Low Temperatures: Experimental and Theoretic Spectroscopy Study

Publication typeJournal Article
Publication date2019-05-07
scimago Q2
wos Q2
SJR0.634
CiteScore4.8
Impact factor2.8
ISSN10895639, 15205215
Physical and Theoretical Chemistry
Abstract
This work is devoted to the discussion of structural changes in crystalline iodine under low temperature studied from experimental and theoretic points of view. Experimental Raman spectra in the temperature range 5-300 K demonstrated unusual behavior of stretching vibration at ∼180 cm-1 with temperature. The data allowed obtaining of ω( T) functions for both external translational and internal stretching modes of I2. It was found that ω( T) trends significantly differ in comparison to typical van der Waals crystal α-S8. The observed anomalies are explained from a theoretic point of view because of the strengthening of intralayer halogen bonding between I2 molecules.
Found 
Found 

Top-30

Journals

1
2
Inorganic Chemistry
2 publications, 20%
Crystal Growth and Design
1 publication, 10%
Crystals
1 publication, 10%
Journal of Molecular Structure
1 publication, 10%
Industrial & Engineering Chemistry Research
1 publication, 10%
Journal of Physical Chemistry C
1 publication, 10%
Journal of Physical Chemistry Letters
1 publication, 10%
Journal of Materials Chemistry C
1 publication, 10%
Dalton Transactions
1 publication, 10%
1
2

Publishers

1
2
3
4
5
6
American Chemical Society (ACS)
6 publications, 60%
Royal Society of Chemistry (RSC)
2 publications, 20%
MDPI
1 publication, 10%
Elsevier
1 publication, 10%
1
2
3
4
5
6
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
10
Share
Cite this
GOST |
Cite this
GOST Copy
Yushina I. D., Kolesov B. Interplay of Intra- and Intermolecular Interactions in Solid Iodine at Low Temperatures: Experimental and Theoretic Spectroscopy Study // Journal of Physical Chemistry A. 2019. Vol. 123. No. 21. pp. 4575-4580.
GOST all authors (up to 50) Copy
Yushina I. D., Kolesov B. Interplay of Intra- and Intermolecular Interactions in Solid Iodine at Low Temperatures: Experimental and Theoretic Spectroscopy Study // Journal of Physical Chemistry A. 2019. Vol. 123. No. 21. pp. 4575-4580.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.jpca.9b01167
UR - https://pubs.acs.org/doi/10.1021/acs.jpca.9b01167
TI - Interplay of Intra- and Intermolecular Interactions in Solid Iodine at Low Temperatures: Experimental and Theoretic Spectroscopy Study
T2 - Journal of Physical Chemistry A
AU - Yushina, Irina D.
AU - Kolesov, B.A.
PY - 2019
DA - 2019/05/07
PB - American Chemical Society (ACS)
SP - 4575-4580
IS - 21
VL - 123
PMID - 31063373
SN - 1089-5639
SN - 1520-5215
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Yushina,
author = {Irina D. Yushina and B.A. Kolesov},
title = {Interplay of Intra- and Intermolecular Interactions in Solid Iodine at Low Temperatures: Experimental and Theoretic Spectroscopy Study},
journal = {Journal of Physical Chemistry A},
year = {2019},
volume = {123},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://pubs.acs.org/doi/10.1021/acs.jpca.9b01167},
number = {21},
pages = {4575--4580},
doi = {10.1021/acs.jpca.9b01167}
}
MLA
Cite this
MLA Copy
Yushina, Irina D., et al. “Interplay of Intra- and Intermolecular Interactions in Solid Iodine at Low Temperatures: Experimental and Theoretic Spectroscopy Study.” Journal of Physical Chemistry A, vol. 123, no. 21, May. 2019, pp. 4575-4580. https://pubs.acs.org/doi/10.1021/acs.jpca.9b01167.