Probing the Surface of Platinum during the Hydrogen Evolution Reaction in Alkaline Electrolyte
Marco Favaro
2, 3, 4
,
Philip N Ross
5
,
Christian Kisielowski
3, 6
,
Zhi Liu
7, 8
,
Zahid Hussain
2
,
Ethan J. Crumlin
2, 9
Publication type: Journal Article
Publication date: 2017-12-06
scimago Q1
wos Q3
SJR: 0.742
CiteScore: 5.3
Impact factor: 2.9
ISSN: 15206106, 15205207, 10895647
PubMed ID:
29166014
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Abstract
Understanding the surface chemistry of electrocatalysts in operando can bring insight into the reaction mechanism, and ultimately the design of more efficient materials for sustainable energy storage and conversion. Recent progress in synchrotron based X-ray spectroscopies for in operando characterization allows us to probe the solid/liquid interface directly while applying an external potential, applied here to the model system of Pt in alkaline electrolyte for the hydrogen evolution reaction (HER). We employ ambient pressure X-ray photoelectron spectroscopy (AP-XPS) to identify the oxidation and reduction of Pt-oxides and hydroxides on the surface as a function of applied potential, and further assess the potential for hydrogen adsorption and absorption (hydride formation) during and after the HER. This new window into the surface chemistry of Pt in alkaline electrolyte brings insight into the nature of the rate limiting step, the extent of H ad/absorption, and its persistence at more anodic potentials.
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64
Total citations:
64
Citations from 2024:
20
(31%)
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GOST
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Stoerzinger K. A. et al. Probing the Surface of Platinum during the Hydrogen Evolution Reaction in Alkaline Electrolyte // Journal of Physical Chemistry B. 2017. Vol. 122. No. 2. pp. 864-870.
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Stoerzinger K. A., Favaro M., Ross P. N., Kisielowski C., Liu Z., Hussain Z., Crumlin E. J. Probing the Surface of Platinum during the Hydrogen Evolution Reaction in Alkaline Electrolyte // Journal of Physical Chemistry B. 2017. Vol. 122. No. 2. pp. 864-870.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.jpcb.7b06953
UR - https://doi.org/10.1021/acs.jpcb.7b06953
TI - Probing the Surface of Platinum during the Hydrogen Evolution Reaction in Alkaline Electrolyte
T2 - Journal of Physical Chemistry B
AU - Stoerzinger, Kelsey A.
AU - Favaro, Marco
AU - Ross, Philip N
AU - Kisielowski, Christian
AU - Liu, Zhi
AU - Hussain, Zahid
AU - Crumlin, Ethan J.
PY - 2017
DA - 2017/12/06
PB - American Chemical Society (ACS)
SP - 864-870
IS - 2
VL - 122
PMID - 29166014
SN - 1520-6106
SN - 1520-5207
SN - 1089-5647
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Stoerzinger,
author = {Kelsey A. Stoerzinger and Marco Favaro and Philip N Ross and Christian Kisielowski and Zhi Liu and Zahid Hussain and Ethan J. Crumlin},
title = {Probing the Surface of Platinum during the Hydrogen Evolution Reaction in Alkaline Electrolyte},
journal = {Journal of Physical Chemistry B},
year = {2017},
volume = {122},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.jpcb.7b06953},
number = {2},
pages = {864--870},
doi = {10.1021/acs.jpcb.7b06953}
}
Cite this
MLA
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Stoerzinger, Kelsey A., et al. “Probing the Surface of Platinum during the Hydrogen Evolution Reaction in Alkaline Electrolyte.” Journal of Physical Chemistry B, vol. 122, no. 2, Dec. 2017, pp. 864-870. https://doi.org/10.1021/acs.jpcb.7b06953.