Journal of Physical Chemistry C, volume 119, issue 50, pages 27882-27891
High-Performance Electrospun Poly(vinylidene fluoride)/Poly(propylene carbonate) Gel Polymer Electrolyte for Lithium-Ion Batteries
Xueyan Huang
1
,
Songshan Zeng
2
,
Jingjing Liu
2
,
Ting He Ting He
1
,
Luyi Sun
2
,
DONGHUI XU
1
,
Xiaoyuan Yu
1
,
Ying Luo
1
,
Wuyi Zhou
1
,
Jianfeng Wu
3
3
State Key Laboratory of Motor Vehicle Biofuel Technology, Nanyang 473000, China
|
Publication type: Journal Article
Publication date: 2015-12-03
Journal:
Journal of Physical Chemistry C
Q1
Q3
SJR: 0.957
CiteScore: 6.5
Impact factor: 3.3
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
A novel high-performance gel polymer electrolyte (GPE) based on an electrospun polymer membrane of poly(vinylidene fluoride)/poly(propylene carbonate) (PVdF/PPC) was prepared and investigated for high-performance lithium-ion battery applications. This study presents a methodology for introducing PPC into PVdF-based GPEs designed for high-performance lithium-ion batteries. SEM images and porosity measurements showed that the electrospun membrane had a uniform and highly interconnected porous structure with an average fiber diameter of 300–850 nm. Such a morphology resulted in excellent electrolyte uptake amount (500 wt %) and retention in PVdF/PPC membrane. The DSC result indicated that the PVdF crystallinity was deteriorated by the incorporation of PPC. The PVdF/PPC electrospun membrane showed significantly higher ionic conductivity (4.05 mS·cm–1) than that of the PVdF electrospun membrane (2.11 mS·cm–1) at 30 °C. The PVdF/PPC GPE was stable at a potential higher than 5.2 V (versus Li+/Li). The capacity o...
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Huang X. et al. High-Performance Electrospun Poly(vinylidene fluoride)/Poly(propylene carbonate) Gel Polymer Electrolyte for Lithium-Ion Batteries // Journal of Physical Chemistry C. 2015. Vol. 119. No. 50. pp. 27882-27891.
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Huang X., Zeng S., Liu J., Ting He T. H., Sun L., XU D., Yu X., Luo Y., Zhou W., Wu J. High-Performance Electrospun Poly(vinylidene fluoride)/Poly(propylene carbonate) Gel Polymer Electrolyte for Lithium-Ion Batteries // Journal of Physical Chemistry C. 2015. Vol. 119. No. 50. pp. 27882-27891.
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TY - JOUR
DO - 10.1021/acs.jpcc.5b09130
UR - https://doi.org/10.1021/acs.jpcc.5b09130
TI - High-Performance Electrospun Poly(vinylidene fluoride)/Poly(propylene carbonate) Gel Polymer Electrolyte for Lithium-Ion Batteries
T2 - Journal of Physical Chemistry C
AU - Huang, Xueyan
AU - Zeng, Songshan
AU - Liu, Jingjing
AU - Ting He, Ting He
AU - Sun, Luyi
AU - XU, DONGHUI
AU - Yu, Xiaoyuan
AU - Luo, Ying
AU - Zhou, Wuyi
AU - Wu, Jianfeng
PY - 2015
DA - 2015/12/03
PB - American Chemical Society (ACS)
SP - 27882-27891
IS - 50
VL - 119
SN - 1932-7447
SN - 1932-7455
ER -
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@article{2015_Huang,
author = {Xueyan Huang and Songshan Zeng and Jingjing Liu and Ting He Ting He and Luyi Sun and DONGHUI XU and Xiaoyuan Yu and Ying Luo and Wuyi Zhou and Jianfeng Wu},
title = {High-Performance Electrospun Poly(vinylidene fluoride)/Poly(propylene carbonate) Gel Polymer Electrolyte for Lithium-Ion Batteries},
journal = {Journal of Physical Chemistry C},
year = {2015},
volume = {119},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.jpcc.5b09130},
number = {50},
pages = {27882--27891},
doi = {10.1021/acs.jpcc.5b09130}
}
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Huang, Xueyan, et al. “High-Performance Electrospun Poly(vinylidene fluoride)/Poly(propylene carbonate) Gel Polymer Electrolyte for Lithium-Ion Batteries.” Journal of Physical Chemistry C, vol. 119, no. 50, Dec. 2015, pp. 27882-27891. https://doi.org/10.1021/acs.jpcc.5b09130.