Toward Safe and Sustainable Batteries: Na4Fe3(PO4)2P2O7 as a Low-Cost Cathode for Rechargeable Aqueous Na-Ion Batteries
1
CIC ENERGIGUNE, Parque Tecnológico de Álava, Albert Einstein 48, ED.CIC, 01510 Miñano, Spain
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Publication type: Journal Article
Publication date: 2017-12-27
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
The electrochemical properties of Na4Fe3(PO4)2P2O7 in aqueous and organic electrolyte are compared under similar conditions. Na4Fe3(PO4)2P2O7 is able to deliver almost the same capacity in both types of electrolytes despite the smaller electrochemical window entailed by the aqueous one. As shown by electrochemical impedance spectroscopy (EIS), this is possible thanks to the lower overpotential that this material exhibits in aqueous electrolyte. It is shown here that the main contribution to overpotential in organic electrolyte mainly originates from a SPI (Solid Permeable Interphase) layer formed below 3.5 V vs Na+/Na that acts as a blocking layer and hinders Na+ diffusion and that is absent in aqueous electrolyte. Overall, the obtained results highlight the positive attributes of using low-cost and environmentally friendly aqueous electrolytes and the challenges to be overcome in terms of air and moisture stability of the studied material.
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Total citations:
64
Citations from 2024:
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(17%)
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GOST
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Fernández Ropero A. J. et al. Toward Safe and Sustainable Batteries: Na4Fe3(PO4)2P2O7 as a Low-Cost Cathode for Rechargeable Aqueous Na-Ion Batteries // Journal of Physical Chemistry C. 2017. Vol. 122. No. 1. pp. 133-142.
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Fernández Ropero A. J., Zarrabeitia M., Reynaud M., Lu J., Casas-Cabanas M. Toward Safe and Sustainable Batteries: Na4Fe3(PO4)2P2O7 as a Low-Cost Cathode for Rechargeable Aqueous Na-Ion Batteries // Journal of Physical Chemistry C. 2017. Vol. 122. No. 1. pp. 133-142.
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TY - JOUR
DO - 10.1021/acs.jpcc.7b09803
UR - https://doi.org/10.1021/acs.jpcc.7b09803
TI - Toward Safe and Sustainable Batteries: Na4Fe3(PO4)2P2O7 as a Low-Cost Cathode for Rechargeable Aqueous Na-Ion Batteries
T2 - Journal of Physical Chemistry C
AU - Fernández Ropero, Antonio J
AU - Zarrabeitia, Maider
AU - Reynaud, Marine
AU - Lu, Jun
AU - Casas-Cabanas, Montse
PY - 2017
DA - 2017/12/27
PB - American Chemical Society (ACS)
SP - 133-142
IS - 1
VL - 122
SN - 1932-7447
SN - 1932-7455
ER -
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@article{2017_Fernández Ropero,
author = {Antonio J Fernández Ropero and Maider Zarrabeitia and Marine Reynaud and Jun Lu and Montse Casas-Cabanas},
title = {Toward Safe and Sustainable Batteries: Na4Fe3(PO4)2P2O7 as a Low-Cost Cathode for Rechargeable Aqueous Na-Ion Batteries},
journal = {Journal of Physical Chemistry C},
year = {2017},
volume = {122},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acs.jpcc.7b09803},
number = {1},
pages = {133--142},
doi = {10.1021/acs.jpcc.7b09803}
}
Cite this
MLA
Copy
Fernández Ropero, Antonio J., et al. “Toward Safe and Sustainable Batteries: Na4Fe3(PO4)2P2O7 as a Low-Cost Cathode for Rechargeable Aqueous Na-Ion Batteries.” Journal of Physical Chemistry C, vol. 122, no. 1, Dec. 2017, pp. 133-142. https://doi.org/10.1021/acs.jpcc.7b09803.
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