Journal of Physical Chemistry C

, том 122 , издание 26 , страницы 14928-14936

New Type of Nanocrystalline Luminescent Thermometers Based on Ti³⁺/Ti⁴⁺ and Ti⁴⁺/Ln³⁺ (Ln³⁺ = Nd³⁺, Eu³⁺, Dy³⁺) Luminescence Intensity Ratio

J Drabik ¹

Bartłomiej Cichy ¹

Lukasz Marciniak ¹

Скрыть аффилиации авторов Показать аффилиации авторов: 1 аффилиация

Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, 50-422 Wroclaw, Poland |

Тип публикации: Journal Article

Дата публикации: 2018-06-12

American Chemical Society (ACS)

Journal of Physical Chemistry C

scimago Q1

wos Q3

БС1

SJR: 0.914

CiteScore: 6.2

Impact factor: 3.2

ISSN: 19327447, 19327455

DOI: 10.1021/acs.jpcc.8b02328

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Surfaces, Coatings and Films

Electronic, Optical and Magnetic Materials

Physical and Theoretical Chemistry

General Energy

Краткое описание

The spectroscopic properties of YAG:Ti and YAG:Ti,Ln nanocrystalline powders were examined as part of the search for new functional materials devoted to luminescent thermometry. Various temperature-dependent processes occurring in the studied systems were analyzed and the mechanism of absorption and emission of trivalent and tetravalent titanium ions was proposed. The first luminescent thermometer based on the Ti4+/Ti3+ luminescence intensity ratio with maximum sensitivity of 0.71% C–1 is shown. It was shown that the codoping with lanthanide ions enhances the relative sensitivity of YAG:Ti,Ln nanocrystalline luminescent thermometers because of the Ti4+ → Ln3+ energy transfer. The maximal relative sensitivities in the physiological range (2.26% C–1 at 50 °C) were found for YAG:Ti,Nd3+ nanocrystals and the value increases with temperature reaching 3.70% C–1 at 200 °C.

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Drabik J., Cichy B., Marciniak L. New Type of Nanocrystalline Luminescent Thermometers Based on Ti3+/Ti4+ and Ti4+/Ln3+ (Ln3+ = Nd3+, Eu3+, Dy3+) Luminescence Intensity Ratio // Journal of Physical Chemistry C. 2018. Vol. 122. No. 26. pp. 14928-14936.

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TY - JOUR

DO - 10.1021/acs.jpcc.8b02328

UR - https://doi.org/10.1021/acs.jpcc.8b02328

TI - New Type of Nanocrystalline Luminescent Thermometers Based on Ti3+/Ti4+ and Ti4+/Ln3+ (Ln3+ = Nd3+, Eu3+, Dy3+) Luminescence Intensity Ratio

T2 - Journal of Physical Chemistry C

AU - Drabik, J

AU - Cichy, Bartłomiej

AU - Marciniak, Lukasz

PY - 2018

DA - 2018/06/12

PB - American Chemical Society (ACS)

SP - 14928-14936

IS - 26

VL - 122

SN - 1932-7447

SN - 1932-7455

ER -

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@article{2018_Drabik,

author = {J Drabik and Bartłomiej Cichy and Lukasz Marciniak},

title = {New Type of Nanocrystalline Luminescent Thermometers Based on Ti3+/Ti4+ and Ti4+/Ln3+ (Ln3+ = Nd3+, Eu3+, Dy3+) Luminescence Intensity Ratio},

journal = {Journal of Physical Chemistry C},

year = {2018},

volume = {122},

publisher = {American Chemical Society (ACS)},

month = {jun},

url = {https://doi.org/10.1021/acs.jpcc.8b02328},

number = {26},

pages = {14928--14936},

doi = {10.1021/acs.jpcc.8b02328}

}

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Drabik, J., et al. “New Type of Nanocrystalline Luminescent Thermometers Based on Ti3+/Ti4+ and Ti4+/Ln3+ (Ln3+ = Nd3+, Eu3+, Dy3+) Luminescence Intensity Ratio.” Journal of Physical Chemistry C, vol. 122, no. 26, Jun. 2018, pp. 14928-14936. https://doi.org/10.1021/acs.jpcc.8b02328.