Effect of Thermal Treatment on the Atomic Structure and Electrochemical Characteristics of Bimetallic PtCu Core–Shell Nanoparticles in PtCu/C Electrocatalysts
Sergey Belenov
1
,
Darya B Shemet
1
,
V. V. Srabionyan
1
,
Leon A. Avakyan
1
,
V.A Volochaev
1
,
A. S. Mikheykin
1, 2
,
Karina E Bdoyan
1
,
Ivo Zizak
3
,
V. E. Guterman
1
,
Lusegen A. Bugaev
1
Publication type: Journal Article
Publication date: 2018-07-05
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
Supported PtCu/C electrocatalysts containing core–shell bimetallic PtCu nanoparticles were synthesized by sequential chemical reduction of Cu2+ and Pt(IV) in a carbon suspension, prepared on the basis of ethylene glycol–water solvent, and then treated at different temperatures in the range from 250 to 350 °C. The structural characterization of “as-prepared” PtCu nanoparticles and of those obtained after the thermal treatments was performed by transmission electron microscopy, X-ray diffraction, and Pt L3- and Cu K-edge extended X-ray absorption fine structure spectroscopy. The atomic cluster models of PtCu nanoparticles before and after the thermal treatment, reflecting the character of the components’ distribution, were generated. The electrochemical performance of the obtained PtCu/C electrocatalysts in oxygen reduction reaction was studied by cycling and linear voltammetry.
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Total citations:
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Citations from 2024:
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(28%)
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GOST
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Pryadchenko V. V. et al. Effect of Thermal Treatment on the Atomic Structure and Electrochemical Characteristics of Bimetallic PtCu Core–Shell Nanoparticles in PtCu/C Electrocatalysts // Journal of Physical Chemistry C. 2018. Vol. 122. No. 30. pp. 17199-17210.
GOST all authors (up to 50)
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Pryadchenko V. V., Belenov S., Shemet D. B., Srabionyan V. V., Avakyan L. A., Volochaev V., Mikheykin A. S., Bdoyan K. E., Zizak I., Guterman V. E., Bugaev L. A. Effect of Thermal Treatment on the Atomic Structure and Electrochemical Characteristics of Bimetallic PtCu Core–Shell Nanoparticles in PtCu/C Electrocatalysts // Journal of Physical Chemistry C. 2018. Vol. 122. No. 30. pp. 17199-17210.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.jpcc.8b03696
UR - https://doi.org/10.1021/acs.jpcc.8b03696
TI - Effect of Thermal Treatment on the Atomic Structure and Electrochemical Characteristics of Bimetallic PtCu Core–Shell Nanoparticles in PtCu/C Electrocatalysts
T2 - Journal of Physical Chemistry C
AU - Pryadchenko, Vasiliy V
AU - Belenov, Sergey
AU - Shemet, Darya B
AU - Srabionyan, V. V.
AU - Avakyan, Leon A.
AU - Volochaev, V.A
AU - Mikheykin, A. S.
AU - Bdoyan, Karina E
AU - Zizak, Ivo
AU - Guterman, V. E.
AU - Bugaev, Lusegen A.
PY - 2018
DA - 2018/07/05
PB - American Chemical Society (ACS)
SP - 17199-17210
IS - 30
VL - 122
SN - 1932-7447
SN - 1932-7455
ER -
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BibTex (up to 50 authors)
Copy
@article{2018_Pryadchenko,
author = {Vasiliy V Pryadchenko and Sergey Belenov and Darya B Shemet and V. V. Srabionyan and Leon A. Avakyan and V.A Volochaev and A. S. Mikheykin and Karina E Bdoyan and Ivo Zizak and V. E. Guterman and Lusegen A. Bugaev},
title = {Effect of Thermal Treatment on the Atomic Structure and Electrochemical Characteristics of Bimetallic PtCu Core–Shell Nanoparticles in PtCu/C Electrocatalysts},
journal = {Journal of Physical Chemistry C},
year = {2018},
volume = {122},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.jpcc.8b03696},
number = {30},
pages = {17199--17210},
doi = {10.1021/acs.jpcc.8b03696}
}
Cite this
MLA
Copy
Pryadchenko, Vasiliy V., et al. “Effect of Thermal Treatment on the Atomic Structure and Electrochemical Characteristics of Bimetallic PtCu Core–Shell Nanoparticles in PtCu/C Electrocatalysts.” Journal of Physical Chemistry C, vol. 122, no. 30, Jul. 2018, pp. 17199-17210. https://doi.org/10.1021/acs.jpcc.8b03696.