volume 11 issue 7 pages 2570-2576

Charge Carrier Recombination Dynamics of Two-Dimensional Lead Halide Perovskites

Publication typeJournal Article
Publication date2020-03-11
scimago Q1
wos Q1
SJR1.394
CiteScore8.7
Impact factor4.6
ISSN19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
Two-dimensional (2D) lead halide perovskites with better chemical stability and tunable dimensionality offer new opportunities to design optoelectronic devices. We have probed the transient absorption behavior of 2D lead halide (bromide and iodide) perovskites of different dimensionality, prepared by varying the ratio of methylammonium:phenylethylammonium cation. With decreasing dimensionality (n =  → 1), we observe a blue shift in transient absorption bleach in agreement with the trend observed with the shift in the excitonic peak. The lifetime of the charge carriers, decreased with decreasing layer thickness. The dependence of charge carrier lifetime on the 2D layers as well as the halide ion composition shows the dominance of excitonic binding energy on the charge carrier recombination in 2D perovskites. The excited state behavior of 2D perovskites discussed in this study shows the need to modulate the layer dimensionality to obtain desired optoelectronic properties.
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GOST Copy
Cho J., DuBose J., Kamat P. V. Charge Carrier Recombination Dynamics of Two-Dimensional Lead Halide Perovskites // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 7. pp. 2570-2576.
GOST all authors (up to 50) Copy
Cho J., DuBose J., Kamat P. V. Charge Carrier Recombination Dynamics of Two-Dimensional Lead Halide Perovskites // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 7. pp. 2570-2576.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.jpclett.0c00392
UR - https://doi.org/10.1021/acs.jpclett.0c00392
TI - Charge Carrier Recombination Dynamics of Two-Dimensional Lead Halide Perovskites
T2 - Journal of Physical Chemistry Letters
AU - Cho, Junsang
AU - DuBose, Jeffrey
AU - Kamat, Prashant V
PY - 2020
DA - 2020/03/11
PB - American Chemical Society (ACS)
SP - 2570-2576
IS - 7
VL - 11
PMID - 32160471
SN - 1948-7185
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Cho,
author = {Junsang Cho and Jeffrey DuBose and Prashant V Kamat},
title = {Charge Carrier Recombination Dynamics of Two-Dimensional Lead Halide Perovskites},
journal = {Journal of Physical Chemistry Letters},
year = {2020},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.jpclett.0c00392},
number = {7},
pages = {2570--2576},
doi = {10.1021/acs.jpclett.0c00392}
}
MLA
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MLA Copy
Cho, Junsang, et al. “Charge Carrier Recombination Dynamics of Two-Dimensional Lead Halide Perovskites.” Journal of Physical Chemistry Letters, vol. 11, no. 7, Mar. 2020, pp. 2570-2576. https://doi.org/10.1021/acs.jpclett.0c00392.