Gas-phase Synthesis and Characterisation of the Methyl-2,2-dicyanoacetate Anion Using Photoelectron Imaging and Dipole-bound State Autodetachment.
Publication type: Journal Article
Publication date: 2020-07-20
scimago Q1
wos Q1
SJR: 1.394
CiteScore: 8.7
Impact factor: 4.6
ISSN: 19487185
PubMed ID:
32687376
Physical and Theoretical Chemistry
General Materials Science
Abstract
The methyl-2,2-dicyanoacetate anion is synthesised in an electrospray ionisation source through a gas-phase reaction involving tetracyanoethylene and methanol. Photoelectron imaging is used to determine the isomeric form of the product. The photoelectron spectra and angular distributions are only consistent with a single isomer. Additionally, mode-specific vibrational autodetachment is observed. This can be correlated with the emission from a photoexcited dipole-bound state by considering the IR spectrum of the neutral molecule, adding further confirmation of the isomeric form and providing a binding energy of the dipole-bound state. Our experiments show how conventional photoelectron imaging can be used to determine detailed information about gas-phase reaction products.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
|
|
|
Journal of Physical Chemistry A
5 publications, 38.46%
|
|
|
Journal of Physical Chemistry Letters
2 publications, 15.38%
|
|
|
Physical Chemistry Chemical Physics
2 publications, 15.38%
|
|
|
European Physical Journal D
1 publication, 7.69%
|
|
|
Accounts of Chemical Research
1 publication, 7.69%
|
|
|
Physical Review Letters
1 publication, 7.69%
|
|
|
1
2
3
4
5
|
Publishers
|
1
2
3
4
5
6
7
8
|
|
|
American Chemical Society (ACS)
8 publications, 61.54%
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 15.38%
|
|
|
Springer Nature
1 publication, 7.69%
|
|
|
American Physical Society (APS)
1 publication, 7.69%
|
|
|
1
2
3
4
5
6
7
8
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
13
Total citations:
13
Citations from 2024:
1
(7%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Anstöter C. S., Verlet J. R. Gas-phase Synthesis and Characterisation of the Methyl-2,2-dicyanoacetate Anion Using Photoelectron Imaging and Dipole-bound State Autodetachment. // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 15. pp. 6456-6462.
GOST all authors (up to 50)
Copy
Anstöter C. S., Verlet J. R. Gas-phase Synthesis and Characterisation of the Methyl-2,2-dicyanoacetate Anion Using Photoelectron Imaging and Dipole-bound State Autodetachment. // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 15. pp. 6456-6462.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.jpclett.0c02036
UR - https://doi.org/10.1021/acs.jpclett.0c02036
TI - Gas-phase Synthesis and Characterisation of the Methyl-2,2-dicyanoacetate Anion Using Photoelectron Imaging and Dipole-bound State Autodetachment.
T2 - Journal of Physical Chemistry Letters
AU - Anstöter, Cate S.
AU - Verlet, Jan R. R.
PY - 2020
DA - 2020/07/20
PB - American Chemical Society (ACS)
SP - 6456-6462
IS - 15
VL - 11
PMID - 32687376
SN - 1948-7185
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Anstöter,
author = {Cate S. Anstöter and Jan R. R. Verlet},
title = {Gas-phase Synthesis and Characterisation of the Methyl-2,2-dicyanoacetate Anion Using Photoelectron Imaging and Dipole-bound State Autodetachment.},
journal = {Journal of Physical Chemistry Letters},
year = {2020},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.jpclett.0c02036},
number = {15},
pages = {6456--6462},
doi = {10.1021/acs.jpclett.0c02036}
}
Cite this
MLA
Copy
Anstöter, Cate S., and Jan R. R. Verlet. “Gas-phase Synthesis and Characterisation of the Methyl-2,2-dicyanoacetate Anion Using Photoelectron Imaging and Dipole-bound State Autodetachment..” Journal of Physical Chemistry Letters, vol. 11, no. 15, Jul. 2020, pp. 6456-6462. https://doi.org/10.1021/acs.jpclett.0c02036.
Profiles