Journal of Physical Chemistry Letters, volume 11, issue 19, pages 8222-8230
Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N≡N Bond Dissociation
Publication type: Journal Article
Publication date: 2020-09-09
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 19487185, 19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
Dinitrogen activation is known as one of the most challenging subjects in chemistry. A number of well-defined metal complexes, nitrides, and clusters have been studied that show catalysis for dinitrogen activation. However, direct evidence of a complete cleavage of the N≡N triple bond at mild conditions is rather limited to date. Herein, we report a study on the dissociation of N2 on small rhodium clusters assisted by surface plasma radiation. From mass spectrometry observation, a few rhodium nitride clusters with an odd number of nitrogen atoms are produced, such as the Rh3N2m-1+ (m = 1-5) series, indicative of N≡N bond dissociation in the mild plasma atmosphere. Interestingly, Rh3N7+ is identified with outstanding mass abundance among the RhnN2m-1+ products, and its ground-state structure is in the form of Rh3N(N2)3+ by capping a nitrogen atom on the top of Rh3+ plane and hanging three N2 molecules beneath the three Rh atoms respectively, giving rise to a C3v symmetry and excellent stability. We demonstrate the catalysis of such a three-atom rhodium cluster and reveal a dinitrogen activation strategy by thermodynamics- and dynamics- favorable chain reactions of multiple N2 molecules with two rhodium clusters under plasma atmosphere.
Top-30
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Citations by publishers
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6 publications, 31.58%
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5 publications, 26.32%
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2 publications, 10.53%
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1 publication, 5.26%
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Springer Nature
1 publication, 5.26%
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1 publication, 5.26%
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- We do not take into account publications without a DOI.
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- Statistics recalculated weekly.
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Cui C. et al. Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N≡N Bond Dissociation // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 19. pp. 8222-8230.
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Cui C., Jia Y., Zhang H., Geng L., Luo Z. Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N≡N Bond Dissociation // Journal of Physical Chemistry Letters. 2020. Vol. 11. No. 19. pp. 8222-8230.
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TY - JOUR
DO - 10.1021/acs.jpclett.0c02218
UR - https://doi.org/10.1021/acs.jpclett.0c02218
TI - Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N≡N Bond Dissociation
T2 - Journal of Physical Chemistry Letters
AU - Jia, Yuhan
AU - Luo, Zhixun
AU - Cui, Chaonan
AU - Zhang, Hanyu
AU - Geng, Lijun
PY - 2020
DA - 2020/09/09 00:00:00
PB - American Chemical Society (ACS)
SP - 8222-8230
IS - 19
VL - 11
SN - 1948-7185
SN - 1948-7185
ER -
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@article{2020_Cui,
author = {Yuhan Jia and Zhixun Luo and Chaonan Cui and Hanyu Zhang and Lijun Geng},
title = {Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N≡N Bond Dissociation},
journal = {Journal of Physical Chemistry Letters},
year = {2020},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.jpclett.0c02218},
number = {19},
pages = {8222--8230},
doi = {10.1021/acs.jpclett.0c02218}
}
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Cui, Chaonan, et al. “Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N≡N Bond Dissociation.” Journal of Physical Chemistry Letters, vol. 11, no. 19, Sep. 2020, pp. 8222-8230. https://doi.org/10.1021/acs.jpclett.0c02218.