Journal of Physical Chemistry Letters, volume 10, issue 4, pages 813-818
γ-Ray-induced degradation in the triple-cation perovskite solar cells
Akbulatov Azat F
2
,
Tsarev Sergey
1
,
Luchkin Sergey
1
,
ZHIDKOV I. S.
3
,
Kurmaev Erst Z
3, 4
,
Troshin Pavel A.
1, 2
Publication type: Journal Article
Publication date: 2019-01-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
We report on the impact of γ radiation (0-500 Gy) on triple-cation Cs0.15MA0.10FA0.75Pb(Br0.17I0.83)3 perovskite solar cells. A set of experiments was designed to reveal the individual contributions of the hole-collecting bottom electrode, perovskite absorber, and electron transport layer (ETL) to the overall solar cell degradation under radiation exposure. We show that the glass/ITO/PEDOT:PSS hole-collecting electrode withstands a 500 Gy dose without any losses in the solar cell performance. In contrast, the perovskite absorber films and PC61BM ETL are very sensitive to γ rays, as can be concluded from the radiation-induced decay of the solar cell efficiency by ∼32-41%. Red shift of the perovskite emission bands and strong enhancement of the photoluminescence suggest that γ rays induce phase segregation of iodine-rich and bromine-rich domains, which represents the first reported example of the radiation-induced halide phase separation in perovskite films. The degradation pathway revealed here emphasizes the need for developing a new generation of metal halide absorbers and ETL materials with improved radiation stability to enable potential space applications of perovskite photovoltaics.
Citations by journals
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1 publication, 2.63%
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1
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Citations by publishers
2
4
6
8
10
12
14
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14 publications, 36.84%
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9 publications, 23.68%
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7 publications, 18.42%
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2 publications, 5.26%
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IOP Publishing
1 publication, 2.63%
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1 publication, 2.63%
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Chinese Physical Society
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Chinese Physical Society
1 publication, 2.63%
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American Institute of Physics (AIP)
|
American Institute of Physics (AIP)
1 publication, 2.63%
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2
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10
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14
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Boldyreva A. G. et al. γ-Ray-induced degradation in the triple-cation perovskite solar cells // Journal of Physical Chemistry Letters. 2019. Vol. 10. No. 4. pp. 813-818.
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Boldyreva A. G., Akbulatov A. F., Tsarev S., Luchkin S., ZHIDKOV I. S., Kurmaev E. Z., Stevenson K. J., Petrov V. G., Troshin P. A. γ-Ray-induced degradation in the triple-cation perovskite solar cells // Journal of Physical Chemistry Letters. 2019. Vol. 10. No. 4. pp. 813-818.
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TY - JOUR
DO - 10.1021/acs.jpclett.8b03222
UR - https://doi.org/10.1021%2Facs.jpclett.8b03222
TI - γ-Ray-induced degradation in the triple-cation perovskite solar cells
T2 - Journal of Physical Chemistry Letters
AU - Kurmaev, Erst Z
AU - ZHIDKOV, I. S.
AU - Stevenson, Keith J
AU - Troshin, Pavel A.
AU - Boldyreva, Aleksandra G
AU - Akbulatov, Azat F
AU - Tsarev, Sergey
AU - Luchkin, Sergey
AU - Petrov, Vladimir G
PY - 2019
DA - 2019/01/08 00:00:00
PB - American Chemical Society (ACS)
SP - 813-818
IS - 4
VL - 10
SN - 1948-7185
ER -
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@article{2019_Boldyreva,
author = {Erst Z Kurmaev and I. S. ZHIDKOV and Keith J Stevenson and Pavel A. Troshin and Aleksandra G Boldyreva and Azat F Akbulatov and Sergey Tsarev and Sergey Luchkin and Vladimir G Petrov},
title = {γ-Ray-induced degradation in the triple-cation perovskite solar cells},
journal = {Journal of Physical Chemistry Letters},
year = {2019},
volume = {10},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Facs.jpclett.8b03222},
number = {4},
pages = {813--818},
doi = {10.1021/acs.jpclett.8b03222}
}
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Boldyreva, Aleksandra G., et al. “γ-Ray-induced degradation in the triple-cation perovskite solar cells.” Journal of Physical Chemistry Letters, vol. 10, no. 4, Jan. 2019, pp. 813-818. https://doi.org/10.1021%2Facs.jpclett.8b03222.