Journal of Physical Chemistry Letters

, volume 10 , issue 20 , pages 6137-6143

Double Rabi Splitting in a Strongly Coupled System of Core–Shell Au@Ag Nanorods and J-Aggregates of Multiple Fluorophores

Dzmitry Melnikau ^{1, 2}

Alexander A. Govyadinov ³

A. Sánchez-Iglesias ^{4, 5}

Marek Grzelczak ^{6, 7}

I.R. Nabiev ^{8, 9}

Luis Liz-Marzan ^{4, 5, 7, 9}

Yury Rakovich ^{6, 7, 9, 10}

Hide authors affiliations Show authors affiliations: 10 affiliations

CIC NanoGUNE, Ave. Tolosa 76, 20018 Donostia-San Sebastian, Spain |

National University of Ireland Galway, University Road, H91 TK33 Galway, Ireland |

neaspec GmbH, Eglfinger Weg 2, Haar 85540, Germany |

⁴

CIC BiomaGUNE, Paseo de Miramón 182, 20014 Donostia-San Sebastián, Spain |

⁵

Biomedical Research Networking Center in Bioengineering, Biomaterials and Nanomedicine, Ciber-BBN, Paseo de Miramón 182, 20014 Donostia-San Sebastián, Spain |

⁶

Donostia International Physics Center (DIPC), Paseo Manuel de Lardizabal 4, 20018 Donostia-San Sebastián, Spain |

⁷

IKERBASQUE, Basque Foundation for Science, Maria Díaz de Haro 3, 48013 Bilbao, Spain |

⁸

Laboratoire de Recherche en Nanosciences, LRN-EA4682, Université de Reims Champagne-Ardenne, 51100 Reims, France |

⁹

National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), 115409 Moscow, Russian Federation |

¹⁰

Centro de Física de Materiales (MPC, CSIC-UPV/EHU) and Departamento de Física de Materiales, UPV-EHU, Paseo Manuel de Lardizabal 5, 20018 Donostia-San Sebastián, Spain

Centro de Física de Materiales

University of the Basque Country

Polytechnic University of Valencia

Publication type: Journal Article

Publication date: 2019-09-26

American Chemical Society (ACS)

Journal of Physical Chemistry Letters

scimago Q1

wos Q1

SJR: 1.394

CiteScore: 8.7

Impact factor: 4.6

ISSN: 19487185

DOI: 10.1021/acs.jpclett.9b01988

Copy DOI

PubMed ID: 31557038

Physical and Theoretical Chemistry

General Materials Science

Abstract

The interaction of several components in the strong coupling regime yielding multiple Rabi splittings opens up remarkable possibilities for studies of multimode hybridization and energy transfer, which is of considerable interest in both fundamental and applied science. Here we demonstrate that three different components, such as core-shell Au@Ag nanorods and J-aggregates of two different dyes, can be integrated into a single hybrid structure, which leads to strong collective exciton-plasmon coupling and double-mode Rabi splitting totaling 338 meV. We demonstrate strong coupling in these multicomponent plexitonic nanostructures by means of magnetic circular dichroism spectroscopy and demonstrate strong magneto-optical activity for the three hybridized states resulting from this coupling. The J-aggregates of two different nonmagnetic dyes interact with metal nanoparticles effectively, achieving magnetic properties due to the hybridization of electronic excitations in the three-component system.

Found

1 citation

Andrianov Evgeniy

🥼

PhD in Physics and Mathematics, associate professor

109 publications, 1 041 citations

h-index: 17

Moscow Institute of Physics and Technology

Institute of Theoretical and Applied Electrodynamics of Russian Academy of Sciences

Dukhov Research Institute of Automatics

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Melnikau D. et al. Double Rabi Splitting in a Strongly Coupled System of Core–Shell Au@Ag Nanorods and J-Aggregates of Multiple Fluorophores // Journal of Physical Chemistry Letters. 2019. Vol. 10. No. 20. pp. 6137-6143.

GOST all authors (up to 50) Copy

Melnikau D., Govyadinov A. A., Sánchez-Iglesias A., Grzelczak M., Nabiev I., Liz-Marzan L., Rakovich Y. Double Rabi Splitting in a Strongly Coupled System of Core–Shell Au@Ag Nanorods and J-Aggregates of Multiple Fluorophores // Journal of Physical Chemistry Letters. 2019. Vol. 10. No. 20. pp. 6137-6143.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acs.jpclett.9b01988

UR - https://doi.org/10.1021/acs.jpclett.9b01988

TI - Double Rabi Splitting in a Strongly Coupled System of Core–Shell Au@Ag Nanorods and J-Aggregates of Multiple Fluorophores

T2 - Journal of Physical Chemistry Letters

AU - Melnikau, Dzmitry

AU - Govyadinov, Alexander A.

AU - Sánchez-Iglesias, A.

AU - Grzelczak, Marek

AU - Nabiev, I.R.

AU - Liz-Marzan, Luis

AU - Rakovich, Yury

PY - 2019

DA - 2019/09/26

PB - American Chemical Society (ACS)

SP - 6137-6143

IS - 20

VL - 10

PMID - 31557038

SN - 1948-7185

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2019_Melnikau,

author = {Dzmitry Melnikau and Alexander A. Govyadinov and A. Sánchez-Iglesias and Marek Grzelczak and I.R. Nabiev and Luis Liz-Marzan and Yury Rakovich},

title = {Double Rabi Splitting in a Strongly Coupled System of Core–Shell Au@Ag Nanorods and J-Aggregates of Multiple Fluorophores},

journal = {Journal of Physical Chemistry Letters},

year = {2019},

volume = {10},

publisher = {American Chemical Society (ACS)},

month = {sep},

url = {https://doi.org/10.1021/acs.jpclett.9b01988},

number = {20},

pages = {6137--6143},

doi = {10.1021/acs.jpclett.9b01988}

}

MLA

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MLA Copy

Melnikau, Dzmitry, et al. “Double Rabi Splitting in a Strongly Coupled System of Core–Shell Au@Ag Nanorods and J-Aggregates of Multiple Fluorophores.” Journal of Physical Chemistry Letters, vol. 10, no. 20, Sep. 2019, pp. 6137-6143. https://doi.org/10.1021/acs.jpclett.9b01988.

Publisher

American Chemical Society (ACS)

Journal

Journal of Physical Chemistry Letters

scimago Q1

wos Q1

SJR

1.394

CiteScore

8.7

Impact factor

4.6

ISSN

19487185 (Print, Electronic)

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