Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions?
Azat F Akbulatov
1
,
Lyubov A Frolova
1, 2
,
Nadezhda N Dremova
1
,
I. S. ZHIDKOV
3
,
V.M Martynenko
1
,
Sergey Tsarev
2
,
Sergey Yu Luchkin
2
,
Ernst Z Kurmaev
3, 4
,
Sergey M. Aldoshin
1
,
Pavel A. Troshin
1, 2
Publication type: Journal Article
Publication date: 2019-12-16
scimago Q1
wos Q1
SJR: 1.394
CiteScore: 8.7
Impact factor: 4.6
ISSN: 19487185
PubMed ID:
31838849
Physical and Theoretical Chemistry
General Materials Science
Abstract
We report the first systematic assessment of intrinsic photothermal stability of a large panel of complex lead halides APbX3 incorporating different univalent cations (A = CH3NH3+, [NH2CHNH2]+, Cs+) and halogen anions (X = Br, I) using a series of analytical techniques such as UV-vis and X-ray photoelectron spectroscopy, X-ray diffraction, EDX analysis, atomic force and scanning electron microscopy, ESR spectroscopy, and mass spectrometry. We show that heat stress and light soaking induce a severe degradation of perovskite films even in the absence of oxygen and moisture. The stability of complex lead halides increases in the order MAPbBr3 < MAPbI3 < FAPbI3 < FAPbBr3 < CsPbI3 < CsPbBr3, thus featuring all-inorganic perovskites as the most promising absorbers for stable perovskite solar cells. An important correlation was found between the stability of the complex lead halides and the volatility of univalent cation halides incorporated in their structure. The established relationship provides useful guidelines for designing new complex metal halides with immensely improved stability.
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128
Total citations:
128
Citations from 2024:
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(35%)
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Akbulatov A. F. et al. Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions? // Journal of Physical Chemistry Letters. 2019. Vol. 11. No. 1. pp. 333-339.
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Akbulatov A. F., Frolova L. A., Dremova N. N., ZHIDKOV I. S., Martynenko V., Tsarev S., Luchkin S. Yu., Kurmaev E. Z., Aldoshin S. M., Stevenson K. J., Troshin P. A. Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions? // Journal of Physical Chemistry Letters. 2019. Vol. 11. No. 1. pp. 333-339.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.jpclett.9b03308
UR - https://pubs.acs.org/doi/10.1021/acs.jpclett.9b03308
TI - Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions?
T2 - Journal of Physical Chemistry Letters
AU - Akbulatov, Azat F
AU - Frolova, Lyubov A
AU - Dremova, Nadezhda N
AU - ZHIDKOV, I. S.
AU - Martynenko, V.M
AU - Tsarev, Sergey
AU - Luchkin, Sergey Yu
AU - Kurmaev, Ernst Z
AU - Aldoshin, Sergey M.
AU - Stevenson, Keith J
AU - Troshin, Pavel A.
PY - 2019
DA - 2019/12/16
PB - American Chemical Society (ACS)
SP - 333-339
IS - 1
VL - 11
PMID - 31838849
SN - 1948-7185
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Akbulatov,
author = {Azat F Akbulatov and Lyubov A Frolova and Nadezhda N Dremova and I. S. ZHIDKOV and V.M Martynenko and Sergey Tsarev and Sergey Yu Luchkin and Ernst Z Kurmaev and Sergey M. Aldoshin and Keith J Stevenson and Pavel A. Troshin},
title = {Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions?},
journal = {Journal of Physical Chemistry Letters},
year = {2019},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.jpclett.9b03308},
number = {1},
pages = {333--339},
doi = {10.1021/acs.jpclett.9b03308}
}
Cite this
MLA
Copy
Akbulatov, Azat F., et al. “Light or Heat: What Is Killing Lead Halide Perovskites under Solar Cell Operation Conditions?.” Journal of Physical Chemistry Letters, vol. 11, no. 1, Dec. 2019, pp. 333-339. https://pubs.acs.org/doi/10.1021/acs.jpclett.9b03308.