Langmuir, volume 32, issue 9, pages 2277-2282

Photochemical Microcontact Printing by Tetrazole Chemistry

Publication typeJournal Article
Publication date2016-02-24
Journal: Langmuir
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor3.9
ISSN07437463, 15205827
Spectroscopy
Electrochemistry
Condensed Matter Physics
General Materials Science
Surfaces and Interfaces
Abstract
We developed a simple method to pattern self-assembled monolayers of tetrazole triethoxylsilane with a variety of different molecules by photochemical microcontact printing. Under irradiation, tetrazoles form highly reactive nitrile imines, which react with alkenes, alkynes, and thiols. The covalent linkage to the surface could be unambiguously demonstrated by fluorescence microscopy, because the reaction product is fluorescent in contrast to tetrazole. The modified surfaces were further analyzed by X-ray photoelectron spectroscopy (XPS), time-of-flight secondary ion mass spectrometry (ToF-SIMS), atomic force microscopy (AFM), and contact angle goniometry. Protein-repellent micropatterns, a biotin-streptavidin array, and structured polymer brushes could be fabricated with this straightforward method for surface functionalization.

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GOST |
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GOST Copy
Vonhören B. et al. Photochemical Microcontact Printing by Tetrazole Chemistry // Langmuir. 2016. Vol. 32. No. 9. pp. 2277-2282.
GOST all authors (up to 50) Copy
Vonhören B., Roling O., Buten C., Körsgen M., Arlinghaus H. F., Ravoo B. J. Photochemical Microcontact Printing by Tetrazole Chemistry // Langmuir. 2016. Vol. 32. No. 9. pp. 2277-2282.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.langmuir.6b00059
UR - https://doi.org/10.1021/acs.langmuir.6b00059
TI - Photochemical Microcontact Printing by Tetrazole Chemistry
T2 - Langmuir
AU - Vonhören, Benjamin
AU - Roling, Oliver
AU - Buten, Christoph
AU - Körsgen, Martin
AU - Arlinghaus, Heinrich F.
AU - Ravoo, Bart Jan
PY - 2016
DA - 2016/02/24 00:00:00
PB - American Chemical Society (ACS)
SP - 2277-2282
IS - 9
VL - 32
SN - 0743-7463
SN - 1520-5827
ER -
BibTex |
Cite this
BibTex Copy
@article{2016_Vonhören,
author = {Benjamin Vonhören and Oliver Roling and Christoph Buten and Martin Körsgen and Heinrich F. Arlinghaus and Bart Jan Ravoo},
title = {Photochemical Microcontact Printing by Tetrazole Chemistry},
journal = {Langmuir},
year = {2016},
volume = {32},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.langmuir.6b00059},
number = {9},
pages = {2277--2282},
doi = {10.1021/acs.langmuir.6b00059}
}
MLA
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MLA Copy
Vonhören, Benjamin, et al. “Photochemical Microcontact Printing by Tetrazole Chemistry.” Langmuir, vol. 32, no. 9, Feb. 2016, pp. 2277-2282. https://doi.org/10.1021/acs.langmuir.6b00059.
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