Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials
Publication type: Journal Article
Publication date: 2017-07-03
scimago Q1
wos Q2
SJR: 0.763
CiteScore: 6.0
Impact factor: 3.9
ISSN: 07437463, 15205827
PubMed ID:
28636393
Spectroscopy
Electrochemistry
Condensed Matter Physics
General Materials Science
Surfaces and Interfaces
Abstract
The charge-transfer kinetics of lithium ion intercalation into LixMn2O4 cathode materials was examined in dilute and concentrated aqueous and carbonate LiTFSI solutions using electrochemical methods. Distinctive trends in ion intercalation rates were observed between water-based and ethylene carbonate/diethyl carbonate solutions. The influence of the solution concentration on the rate of lithium ion transfer in aqueous media can be tentatively attributed to the process associated with Mn dissolution, whereas in carbonate solutions the rate is influenced by the formation of a concentration-dependent solid electrolyte interface (SEI). Some indications of SEI layer formation at electrode surfaces in carbonate solutions after cycling are detected by X-ray photoelectron spectroscopy. The general consequences related to the application of superconcentrated electrolytes for use in advanced energy storage cathodes are outlined and discussed.
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33
Total citations:
33
Citations from 2024:
4
(12%)
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GOST
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Nikitina V. A. et al. Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials // Langmuir. 2017. Vol. 33. No. 37. pp. 9378-9389.
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Nikitina V. A., Zakharkin M. V., Vassiliev S. Y., Yashina L. V., Antipov E. V., Stevenson K. J. Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials // Langmuir. 2017. Vol. 33. No. 37. pp. 9378-9389.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.langmuir.7b01016
UR - https://pubs.acs.org/doi/10.1021/acs.langmuir.7b01016
TI - Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials
T2 - Langmuir
AU - Nikitina, Victoria A.
AU - Zakharkin, Maxim V.
AU - Vassiliev, Sergey Yu.
AU - Yashina, Lada V.
AU - Antipov, Evgeny V.
AU - Stevenson, Keith J
PY - 2017
DA - 2017/07/03
PB - American Chemical Society (ACS)
SP - 9378-9389
IS - 37
VL - 33
PMID - 28636393
SN - 0743-7463
SN - 1520-5827
ER -
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BibTex (up to 50 authors)
Copy
@article{2017_Nikitina,
author = {Victoria A. Nikitina and Maxim V. Zakharkin and Sergey Yu. Vassiliev and Lada V. Yashina and Evgeny V. Antipov and Keith J Stevenson},
title = {Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials},
journal = {Langmuir},
year = {2017},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/acs.langmuir.7b01016},
number = {37},
pages = {9378--9389},
doi = {10.1021/acs.langmuir.7b01016}
}
Cite this
MLA
Copy
Nikitina, Victoria A., et al. “Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials.” Langmuir, vol. 33, no. 37, Jul. 2017, pp. 9378-9389. https://pubs.acs.org/doi/10.1021/acs.langmuir.7b01016.