Langmuir, volume 33, issue 37, pages 9378-9389
Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials
Publication type: Journal Article
Publication date: 2017-07-03
Spectroscopy
Electrochemistry
Condensed Matter Physics
General Materials Science
Surfaces and Interfaces
Abstract
The charge-transfer kinetics of lithium ion intercalation into LixMn2O4 cathode materials was examined in dilute and concentrated aqueous and carbonate LiTFSI solutions using electrochemical methods. Distinctive trends in ion intercalation rates were observed between water-based and ethylene carbonate/diethyl carbonate solutions. The influence of the solution concentration on the rate of lithium ion transfer in aqueous media can be tentatively attributed to the process associated with Mn dissolution, whereas in carbonate solutions the rate is influenced by the formation of a concentration-dependent solid electrolyte interface (SEI). Some indications of SEI layer formation at electrode surfaces in carbonate solutions after cycling are detected by X-ray photoelectron spectroscopy. The general consequences related to the application of superconcentrated electrolytes for use in advanced energy storage cathodes are outlined and discussed.
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Electrochimica Acta
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7 publications, 24.14%
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Journal of the Electrochemical Society
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2 publications, 6.9%
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ACS applied materials & interfaces
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2 publications, 6.9%
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1 publication, 3.45%
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ACS Applied Energy Materials
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1 publication, 3.45%
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Advanced Energy Materials
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1 publication, 3.45%
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Molecules
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Molecules
1 publication, 3.45%
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International Journal of Hydrogen Energy
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1 publication, 3.45%
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Energy Storage Materials
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1 publication, 3.45%
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Journal of Materials Science and Technology
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1 publication, 3.45%
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Journal of Energy Storage
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1 publication, 3.45%
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Advanced Materials Interfaces
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1 publication, 3.45%
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RSC Advances
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RSC Advances
1 publication, 3.45%
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1 publication, 3.45%
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Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics
1 publication, 3.45%
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Journal of Industrial and Engineering Chemistry
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Journal of Industrial and Engineering Chemistry, 1, 3.45%
Journal of Industrial and Engineering Chemistry
1 publication, 3.45%
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Chemistry
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Chemistry
1 publication, 3.45%
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Corrosion Engineering Science and Technology
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Corrosion Engineering Science and Technology
1 publication, 3.45%
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Batteries & Supercaps
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Batteries & Supercaps
1 publication, 3.45%
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Citations by publishers
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Elsevier
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Elsevier
10 publications, 34.48%
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Wiley
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4 publications, 13.79%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
3 publications, 10.34%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
3 publications, 10.34%
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The Electrochemical Society
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2 publications, 6.9%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 6.9%
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Springer Nature
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Springer Nature
1 publication, 3.45%
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Korean Society of Industrial Engineering Chemistry
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Korean Society of Industrial Engineering Chemistry, 1, 3.45%
Korean Society of Industrial Engineering Chemistry
1 publication, 3.45%
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Taylor & Francis
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Taylor & Francis
1 publication, 3.45%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Nikitina V. A. et al. Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials // Langmuir. 2017. Vol. 33. No. 37. pp. 9378-9389.
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Nikitina V. A., Zakharkin M. V., Vassiliev S. Y., Yashina L. V., Antipov E. V., Stevenson K. J. Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials // Langmuir. 2017. Vol. 33. No. 37. pp. 9378-9389.
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TY - JOUR
DO - 10.1021/acs.langmuir.7b01016
UR - https://doi.org/10.1021%2Facs.langmuir.7b01016
TI - Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials
T2 - Langmuir
AU - Nikitina, Victoria A.
AU - Yashina, Lada V.
AU - Zakharkin, Maxim V.
AU - Vassiliev, Sergey Yu.
AU - Antipov, Evgeny V.
AU - Stevenson, Keith J
PY - 2017
DA - 2017/07/03 00:00:00
PB - American Chemical Society (ACS)
SP - 9378-9389
IS - 37
VL - 33
SN - 0743-7463
SN - 1520-5827
ER -
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@article{2017_Nikitina,
author = {Victoria A. Nikitina and Lada V. Yashina and Maxim V. Zakharkin and Sergey Yu. Vassiliev and Evgeny V. Antipov and Keith J Stevenson},
title = {Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials},
journal = {Langmuir},
year = {2017},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021%2Facs.langmuir.7b01016},
number = {37},
pages = {9378--9389},
doi = {10.1021/acs.langmuir.7b01016}
}
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MLA
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Nikitina, Victoria A., et al. “Lithium Ion Coupled Electron-Transfer Rates in Superconcentrated Electrolytes: Exploring the Bottlenecks for Fast Charge-Transfer Rates with LiMn2O4 Cathode Materials.” Langmuir, vol. 33, no. 37, Jul. 2017, pp. 9378-9389. https://doi.org/10.1021%2Facs.langmuir.7b01016.