Nitroxide-Mediated Polymerization of Vinyl Chloride at Low Temperature: Kinetic and Computational Studies
Carlos M R Abreu
1
,
P V Mendonça
1
,
Arménio C. Serra
1
,
Benjamin T. Noble
2
,
Tamaz Guliashvili
3
,
Julien Nicolas
4
,
Jorge F. J. Coelho
1
2
3
Cytosorbents Inc., 7 Deer Park Drive, Monmouth
Junction, New Jersey 08852-192, United States
|
4
Institut
Galien Paris-Sud, CNRS UMR 8612, Univ Paris-Sud, Faculté de Pharmacie, 5 rue Jean-Baptiste Clément, F-92296, Châtenay-Malabry, Cedex, France
|
Тип публикации: Journal Article
Дата публикации: 2016-01-14
scimago Q1
wos Q1
БС1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
The synthesis of poly(vinyl chloride) (PVC) by nitroxide-mediated polymerization (NMP) using the SG1-based BlocBuilder alkoxyamine at low temperature (30 and 42 °C) is reported. The reaction system was studied regarding the nature of the solvent, the monomer-to-solvent ratio, the polymerization temperature, and the target molecular weight. First-order kinetics and linear evolutions of the molecular weight with vinyl chloride (VC) conversion were obtained in dichloromethane (DCM) and dimethyl sulfoxide (DMSO) together with decreasing dispersities (Đ) down to 1.59–1.47. The resulting PVC was fully characterized by 1H nuclear magnetic resonance spectroscopy (1H NMR), 31P NMR, and size exclusion chromatography (SEC). The 1H NMR and 31P NMR revealed the existence of very small content of structural defects and the presence of chain-end functional groups (∼91% SG1 chain-end functionality). Chain extension experiments were performed with VC, methyl methacrylate (MMA), and a mixture of monomers (90% of MMA and 10...
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Abreu C. M. R. et al. Nitroxide-Mediated Polymerization of Vinyl Chloride at Low Temperature: Kinetic and Computational Studies // Macromolecules. 2016. Vol. 49. No. 2. pp. 490-498.
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Abreu C. M. R., Mendonça P. V., Serra A. C., Noble B. T., Guliashvili T., Nicolas J., Coote M. L., Coelho J. F. J. Nitroxide-Mediated Polymerization of Vinyl Chloride at Low Temperature: Kinetic and Computational Studies // Macromolecules. 2016. Vol. 49. No. 2. pp. 490-498.
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TY - JOUR
DO - 10.1021/acs.macromol.5b02017
UR - https://doi.org/10.1021/acs.macromol.5b02017
TI - Nitroxide-Mediated Polymerization of Vinyl Chloride at Low Temperature: Kinetic and Computational Studies
T2 - Macromolecules
AU - Abreu, Carlos M R
AU - Mendonça, P V
AU - Serra, Arménio C.
AU - Noble, Benjamin T.
AU - Guliashvili, Tamaz
AU - Nicolas, Julien
AU - Coote, Michelle L.
AU - Coelho, Jorge F. J.
PY - 2016
DA - 2016/01/14
PB - American Chemical Society (ACS)
SP - 490-498
IS - 2
VL - 49
SN - 0024-9297
SN - 1520-5835
ER -
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@article{2016_Abreu,
author = {Carlos M R Abreu and P V Mendonça and Arménio C. Serra and Benjamin T. Noble and Tamaz Guliashvili and Julien Nicolas and Michelle L. Coote and Jorge F. J. Coelho},
title = {Nitroxide-Mediated Polymerization of Vinyl Chloride at Low Temperature: Kinetic and Computational Studies},
journal = {Macromolecules},
year = {2016},
volume = {49},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.macromol.5b02017},
number = {2},
pages = {490--498},
doi = {10.1021/acs.macromol.5b02017}
}
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MLA
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Abreu, Carlos M. R., et al. “Nitroxide-Mediated Polymerization of Vinyl Chloride at Low Temperature: Kinetic and Computational Studies.” Macromolecules, vol. 49, no. 2, Jan. 2016, pp. 490-498. https://doi.org/10.1021/acs.macromol.5b02017.