Polyethylene–Poly(ethylene oxide) Hybrid Films Obtained by Crazing and Their Structural Peculiarities
Dmitry V. Bagrov
2
,
V Artem V Bakirov
3, 4
,
B.N. Tarasevich
1
,
Tatiana E Grohovskaya
1
,
Larisa M Yarysheva
1
,
S. N. Chvalun
3, 4
,
Aleksandr L Volynskii
1
1
2
3
Publication type: Journal Article
Publication date: 2017-03-24
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Hybrid films have been obtained by crazing high-density polyethylene (HDPE) in a poly(ethylene oxide) (PEO) solution. Deformation by the crazing mechanism gives rise to the formation of a nanoporous structure in HDPE, with the PEO solution penetrating into it. A uniform HDPE–PEO hybrid film is obtained after the solvent is removed. The structure of crazed HDPE has been shown to govern the structure of incorporated PEO. By wide-angle X-ray scattering (WAXS), differential scanning calorimetry (DSC), and Fourier transform infrared spectroscopy (FTIR), we have found out, that PEO crystallization in HDPE film is accompanied by an orientation and a decrease in the crystallinity and melting temperature of PEO due to the spatial confinements caused by the nanoporous HDPE matrix. The revealed effects depend on the pore size, which is, in turn, determined by the degree of HDPE deformation (tensile strain). The lower the strain (HDPE pore size), the greater the decrease in the crystallinity of incorporated PEO. As t...
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Total citations:
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Citations from 2024:
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(20%)
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Yarysheva A. Yu. et al. Polyethylene–Poly(ethylene oxide) Hybrid Films Obtained by Crazing and Their Structural Peculiarities // Macromolecules. 2017. Vol. 50. No. 7. pp. 2881-2888.
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Yarysheva A. Yu., Bagrov D. V., Bakirov V. A. V., Tarasevich B., Grohovskaya T. E., Yarysheva L. M., Chvalun S. N., Volynskii A. L. Polyethylene–Poly(ethylene oxide) Hybrid Films Obtained by Crazing and Their Structural Peculiarities // Macromolecules. 2017. Vol. 50. No. 7. pp. 2881-2888.
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RIS
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TY - JOUR
DO - 10.1021/acs.macromol.6b02512
UR - https://doi.org/10.1021/acs.macromol.6b02512
TI - Polyethylene–Poly(ethylene oxide) Hybrid Films Obtained by Crazing and Their Structural Peculiarities
T2 - Macromolecules
AU - Yarysheva, Alena Yu
AU - Bagrov, Dmitry V.
AU - Bakirov, V Artem V
AU - Tarasevich, B.N.
AU - Grohovskaya, Tatiana E
AU - Yarysheva, Larisa M
AU - Chvalun, S. N.
AU - Volynskii, Aleksandr L
PY - 2017
DA - 2017/03/24
PB - American Chemical Society (ACS)
SP - 2881-2888
IS - 7
VL - 50
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (up to 50 authors)
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@article{2017_Yarysheva,
author = {Alena Yu Yarysheva and Dmitry V. Bagrov and V Artem V Bakirov and B.N. Tarasevich and Tatiana E Grohovskaya and Larisa M Yarysheva and S. N. Chvalun and Aleksandr L Volynskii},
title = {Polyethylene–Poly(ethylene oxide) Hybrid Films Obtained by Crazing and Their Structural Peculiarities},
journal = {Macromolecules},
year = {2017},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.macromol.6b02512},
number = {7},
pages = {2881--2888},
doi = {10.1021/acs.macromol.6b02512}
}
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MLA
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Yarysheva, Alena Yu., et al. “Polyethylene–Poly(ethylene oxide) Hybrid Films Obtained by Crazing and Their Structural Peculiarities.” Macromolecules, vol. 50, no. 7, Mar. 2017, pp. 2881-2888. https://doi.org/10.1021/acs.macromol.6b02512.