Macromolecules, volume 50, issue 20, pages 7895-7900
Cationic Co–Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide
Publication type: Journal Article
Publication date: 2017-10-06
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
For the copolymerization of cyclohexene oxide (CHO) with phthalic anhydride (PA), cationic complex [Co(III)(dmap)2–Salphen][BF4] (3) showed higher activity than a combination of Co–Salphen–Cl (2) with 1 equiv of DMAP. The catalytic activity was further improved by using a bimetallic complex 5 in which the Co(III)(dmap)2–Salphen moiety was bridged by a 1,2,5,6-substituted naphthalene linker. A similar trend of catalytic activity was detected for the copolymerization of CHO with CO2.
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Hatazawa M. et al. Cationic Co–Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide // Macromolecules. 2017. Vol. 50. No. 20. pp. 7895-7900.
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Hatazawa M., Takahashi R., Deng J., Houjou H., Nozaki K. Cationic Co–Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide // Macromolecules. 2017. Vol. 50. No. 20. pp. 7895-7900.
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TY - JOUR
DO - 10.1021/acs.macromol.7b01130
UR - https://doi.org/10.1021/acs.macromol.7b01130
TI - Cationic Co–Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide
T2 - Macromolecules
AU - Hatazawa, Masahiro
AU - Takahashi, Rei
AU - Deng, Jingyuan
AU - Houjou, H.
AU - Nozaki, Kyoko
PY - 2017
DA - 2017/10/06
PB - American Chemical Society (ACS)
SP - 7895-7900
IS - 20
VL - 50
SN - 0024-9297
SN - 1520-5835
ER -
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@article{2017_Hatazawa,
author = {Masahiro Hatazawa and Rei Takahashi and Jingyuan Deng and H. Houjou and Kyoko Nozaki},
title = {Cationic Co–Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide},
journal = {Macromolecules},
year = {2017},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.macromol.7b01130},
number = {20},
pages = {7895--7900},
doi = {10.1021/acs.macromol.7b01130}
}
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Hatazawa, Masahiro, et al. “Cationic Co–Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide.” Macromolecules, vol. 50, no. 20, Oct. 2017, pp. 7895-7900. https://doi.org/10.1021/acs.macromol.7b01130.