volume 51 issue 17 pages 6561-6570

Preparation of Transparent and Flexible Shape Memory Polybenzoxazine Film through Chemical Structure Manipulation and Hydrogen Bonding Control

Publication typeJournal Article
Publication date2018-08-20
scimago Q1
wos Q1
SJR1.352
CiteScore9.0
Impact factor5.2
ISSN00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Polybenzoxazines consisting of chemical structures that differ from conventional polybenzoxazines were obtained at relatively lower temperature with the aid of Lewis acids. It is confirmed by FTIR spectra that the new polybenzoxazines mainly consist of arylamine Mannich-type linkage other than phenolic Mannich-type linkage in conventional polybenzoxazines. Owing to the unique chemical structures, the arylamine Mannich polybenzoxazines possess more weak −OH···π hydrogen bonding but less strong and rigid chelated hydrogen bonding. As a result of the special chemical structures and hydrogen bonding distribution, the arylamine Mannich polybenzoxazines possess many unique properties. For example, they are more flexible. Tensile tests show that the arylamine Mannich polybenzoxazines could be stronger and tougher than phenolic Mannich polybenzoxazine. The highest tensile strength increases 83% while elongation at break value increases 115% for 002P180 (arylamine Mannich polybenzoxazine) compared with PBA-a200 (p...
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GOST |
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GOST Copy
Zhang S. et al. Preparation of Transparent and Flexible Shape Memory Polybenzoxazine Film through Chemical Structure Manipulation and Hydrogen Bonding Control // Macromolecules. 2018. Vol. 51. No. 17. pp. 6561-6570.
GOST all authors (up to 50) Copy
Zhang S., Ran Q. Z., Fu Q., Gu Y. Preparation of Transparent and Flexible Shape Memory Polybenzoxazine Film through Chemical Structure Manipulation and Hydrogen Bonding Control // Macromolecules. 2018. Vol. 51. No. 17. pp. 6561-6570.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.macromol.8b01671
UR - https://doi.org/10.1021/acs.macromol.8b01671
TI - Preparation of Transparent and Flexible Shape Memory Polybenzoxazine Film through Chemical Structure Manipulation and Hydrogen Bonding Control
T2 - Macromolecules
AU - Zhang, Shuai
AU - Ran, Q Z
AU - Fu, Qiang
AU - Gu, Yi
PY - 2018
DA - 2018/08/20
PB - American Chemical Society (ACS)
SP - 6561-6570
IS - 17
VL - 51
SN - 0024-9297
SN - 1520-5835
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Zhang,
author = {Shuai Zhang and Q Z Ran and Qiang Fu and Yi Gu},
title = {Preparation of Transparent and Flexible Shape Memory Polybenzoxazine Film through Chemical Structure Manipulation and Hydrogen Bonding Control},
journal = {Macromolecules},
year = {2018},
volume = {51},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.macromol.8b01671},
number = {17},
pages = {6561--6570},
doi = {10.1021/acs.macromol.8b01671}
}
MLA
Cite this
MLA Copy
Zhang, Shuai, et al. “Preparation of Transparent and Flexible Shape Memory Polybenzoxazine Film through Chemical Structure Manipulation and Hydrogen Bonding Control.” Macromolecules, vol. 51, no. 17, Aug. 2018, pp. 6561-6570. https://doi.org/10.1021/acs.macromol.8b01671.