Open Access
Nano Letters, volume 21, issue 3, pages 1320-1326
Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays
Publication type: Journal Article
Publication date: 2021-01-27
Journal:
Nano Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 10.8
ISSN: 15306984, 15306992
PubMed ID:
33502874
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Bioengineering
Abstract
Vibrational strong coupling is emerging as a promising tool to modify molecular properties by making use of hybrid light–matter states known as polaritons. Fabry–Perot cavities filled with organic molecules are typically used, and the molecular concentration limits the maximum reachable coupling strength. Developing methods to increase the coupling strength beyond the molecular concentration limit are highly desirable. In this Letter, we investigate the effect of adding a gold nanorod array into a cavity containing pure organic molecules using FT-IR microscopy and numerical modeling. Incorporation of the plasmonic nanorod array that acts as artificial molecules leads to an order of magnitude increase in the total coupling strength for the cavity with matching resonant frequency filled with organic molecules. Additionally, we observe a significant narrowing of the plasmon line width inside the cavity. We anticipate that these results will be a step forward in exploring vibropolaritonic chemistry and may be used in plasmon based biosensors.
Citations by journals
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Chemical Reviews
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Chemical Reviews
3 publications, 15%
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Journal of Physical Chemistry Letters
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2 publications, 10%
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Nanophotonics
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1 publication, 5%
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Journal Physics D: Applied Physics
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1 publication, 5%
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Physica Status Solidi (B): Basic Research
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1 publication, 5%
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Journal of Physical Chemistry C
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1 publication, 5%
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Energy and Environmental Science
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1 publication, 5%
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Physical Chemistry Chemical Physics
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1 publication, 5%
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Annual Review of Physical Chemistry
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1 publication, 5%
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Proceedings of the National Academy of Sciences of the United States of America
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Proceedings of the National Academy of Sciences of the United States of America
1 publication, 5%
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Nature Communications
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Nature Communications
1 publication, 5%
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Physical Review B
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Physical Review B
1 publication, 5%
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Optics Express
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Optics Express
1 publication, 5%
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Chemical Physics Reviews
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1 publication, 5%
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Journal of Physical Chemistry A
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Journal of Physical Chemistry A
1 publication, 5%
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Citations by publishers
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American Chemical Society (ACS)
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American Chemical Society (ACS)
7 publications, 35%
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Walter de Gruyter
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Walter de Gruyter
2 publications, 10%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
2 publications, 10%
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Elsevier
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Elsevier
1 publication, 5%
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IOP Publishing
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IOP Publishing
1 publication, 5%
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Wiley
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Wiley
1 publication, 5%
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Annual Reviews
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Annual Reviews
1 publication, 5%
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Proceedings of the National Academy of Sciences (PNAS)
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Proceedings of the National Academy of Sciences (PNAS)
1 publication, 5%
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Springer Nature
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Springer Nature
1 publication, 5%
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American Physical Society (APS)
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American Physical Society (APS)
1 publication, 5%
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Optical Society of America
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Optical Society of America
1 publication, 5%
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American Institute of Physics (AIP)
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American Institute of Physics (AIP)
1 publication, 5%
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- We do not take into account publications that without a DOI.
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- Statistics recalculated weekly.
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Hertzog M. et al. Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays // Nano Letters. 2021. Vol. 21. No. 3. pp. 1320-1326.
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Hertzog M., Munkhbat B., Krasnok A. E., Shegai T. O., Börjesson K. Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays // Nano Letters. 2021. Vol. 21. No. 3. pp. 1320-1326.
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TY - JOUR
DO - 10.1021/acs.nanolett.0c04014
UR - https://doi.org/10.1021%2Facs.nanolett.0c04014
TI - Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays
T2 - Nano Letters
AU - Shegai, Timur O.
AU - Börjesson, Karl
AU - Hertzog, Manuel
AU - Munkhbat, Battulga
AU - Krasnok, A E
PY - 2021
DA - 2021/01/27 00:00:00
PB - American Chemical Society (ACS)
SP - 1320-1326
IS - 3
VL - 21
PMID - 33502874
SN - 1530-6984
SN - 1530-6992
ER -
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@article{2021_Hertzog,
author = {Timur O. Shegai and Karl Börjesson and Manuel Hertzog and Battulga Munkhbat and A E Krasnok},
title = {Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays},
journal = {Nano Letters},
year = {2021},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Facs.nanolett.0c04014},
number = {3},
pages = {1320--1326},
doi = {10.1021/acs.nanolett.0c04014}
}
Cite this
MLA
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Hertzog, Manuel, et al. “Enhancing Vibrational Light-Matter Coupling Strength beyond the Molecular Concentration Limit Using Plasmonic Arrays.” Nano Letters, vol. 21, no. 3, Jan. 2021, pp. 1320-1326. https://doi.org/10.1021%2Facs.nanolett.0c04014.