Nano Letters, volume 15, issue 9, pages 5888-5892

New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon

Publication typeJournal Article
Publication date2015-08-05
Journal: Nano Letters
Q1
Q1
SJR3.411
CiteScore16.8
Impact factor9.6
ISSN15306984, 15306992
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Bioengineering
Abstract
Nongraphitizable carbon, also known as hard carbon, is considered one of the most promising anodes for the emerging Na-ion batteries. The current mechanistic understanding of Na-ion storage in hard carbon is based on the "card-house" model first raised in the early 2000s. This model describes that Na-ion insertion occurs first through intercalation between graphene sheets in turbostratic nanodomains, followed by Na filling of the pores in the carbon structure. We tried to test this model by tuning the sizes of turbostratic nanodomains but revealed a correlation between the structural defects and Na-ion storage. Based on our experimental data, we propose an alternative perspective for sodiation of hard carbon that consists of Na-ion storage at defect sites, by intercalation and last via pore-filling.
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Cite this
GOST |
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GOST Copy
Bommier C. et al. New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon // Nano Letters. 2015. Vol. 15. No. 9. pp. 5888-5892.
GOST all authors (up to 50) Copy
Bommier C., Surta T. W., Dolgos M., Ji X. New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon // Nano Letters. 2015. Vol. 15. No. 9. pp. 5888-5892.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.nanolett.5b01969
UR - https://doi.org/10.1021/acs.nanolett.5b01969
TI - New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon
T2 - Nano Letters
AU - Bommier, Clement
AU - Surta, Todd Wesley
AU - Dolgos, Michelle
AU - Ji, Xiulei
PY - 2015
DA - 2015/08/05
PB - American Chemical Society (ACS)
SP - 5888-5892
IS - 9
VL - 15
SN - 1530-6984
SN - 1530-6992
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Bommier,
author = {Clement Bommier and Todd Wesley Surta and Michelle Dolgos and Xiulei Ji},
title = {New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon},
journal = {Nano Letters},
year = {2015},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.nanolett.5b01969},
number = {9},
pages = {5888--5892},
doi = {10.1021/acs.nanolett.5b01969}
}
MLA
Cite this
MLA Copy
Bommier, Clement, et al. “New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon.” Nano Letters, vol. 15, no. 9, Aug. 2015, pp. 5888-5892. https://doi.org/10.1021/acs.nanolett.5b01969.
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