Nano Letters, volume 20, issue 3, pages 1607-1613
Behavior of Solid Electrolyte in Li-Polymer Battery with NMC Cathode via in-Situ Scanning Electron Microscopy
Shirin Kaboli
1
,
Hendrix Demers
1
,
Andrea Paolella
1
,
Ali Darwiche
1
,
Martin Dontigny
1
,
Daniel Clément
1
,
Abdelbast Guerfi
1
,
Michel Trudeau
1
,
John Goodenough
2
,
1
Hydro-Québec’s Center of Excellence in Transportation Electrification and Energy Storage, Varennes, Québec J3X 1S1, Canada
|
Publication type: Journal Article
Publication date: 2020-02-04
Journal:
Nano Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 10.8
ISSN: 15306984, 15306992
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Bioengineering
Abstract
We present the first results of in situ scanning electron microscopy (SEM) of an all-solid Li battery with a nickel-manganese-cobalt-oxide (NMC-622) cathode at 50 °C and an operating voltage of 2.7-4.3 V. Experiments were conducted under a constant current at several C rates (nC rate: cycling in 1/n h): C/12, C/6, and C/3. The microstructure evolution during cycling was monitored by continuous secondary electron imaging. We found that the chemical degradation of the solid polymer electrolyte (SPE) was the main mechanism for battery failure. This degradation was observed in the form of a gradual thinning of the SPE as a function of cycling time, resulting in gas generation from the cell. We also present various dynamic electrochemical and mechanical phenomena, as observed by SEM images, and compare the performance of this battery with that of an all-solid Li battery with a LiFePO4 cathode.
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Citations by publishers
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5
10
15
20
25
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Wiley
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Elsevier
20 publications, 22.73%
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IOP Publishing
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American Association for the Advancement of Science (AAAS)
1 publication, 1.14%
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Trans Tech Publications
1 publication, 1.14%
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Taylor & Francis
1 publication, 1.14%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.14%
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20
25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kaboli S. et al. Behavior of Solid Electrolyte in Li-Polymer Battery with NMC Cathode via in-Situ Scanning Electron Microscopy // Nano Letters. 2020. Vol. 20. No. 3. pp. 1607-1613.
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Kaboli S., Demers H., Paolella A., Darwiche A., Dontigny M., Clément D., Guerfi A., Trudeau M., Goodenough J., Zaghib K. Behavior of Solid Electrolyte in Li-Polymer Battery with NMC Cathode via in-Situ Scanning Electron Microscopy // Nano Letters. 2020. Vol. 20. No. 3. pp. 1607-1613.
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TY - JOUR
DO - 10.1021/acs.nanolett.9b04452
UR - https://doi.org/10.1021/acs.nanolett.9b04452
TI - Behavior of Solid Electrolyte in Li-Polymer Battery with NMC Cathode via in-Situ Scanning Electron Microscopy
T2 - Nano Letters
AU - Clément, Daniel
AU - Goodenough, John
AU - Zaghib, Karim
AU - Kaboli, Shirin
AU - Demers, Hendrix
AU - Paolella, Andrea
AU - Darwiche, Ali
AU - Dontigny, Martin
AU - Guerfi, Abdelbast
AU - Trudeau, Michel
PY - 2020
DA - 2020/02/04 00:00:00
PB - American Chemical Society (ACS)
SP - 1607-1613
IS - 3
VL - 20
SN - 1530-6984
SN - 1530-6992
ER -
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@article{2020_Kaboli,
author = {Daniel Clément and John Goodenough and Karim Zaghib and Shirin Kaboli and Hendrix Demers and Andrea Paolella and Ali Darwiche and Martin Dontigny and Abdelbast Guerfi and Michel Trudeau},
title = {Behavior of Solid Electrolyte in Li-Polymer Battery with NMC Cathode via in-Situ Scanning Electron Microscopy},
journal = {Nano Letters},
year = {2020},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.nanolett.9b04452},
number = {3},
pages = {1607--1613},
doi = {10.1021/acs.nanolett.9b04452}
}
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MLA
Copy
Kaboli, Shirin, et al. “Behavior of Solid Electrolyte in Li-Polymer Battery with NMC Cathode via in-Situ Scanning Electron Microscopy.” Nano Letters, vol. 20, no. 3, Feb. 2020, pp. 1607-1613. https://doi.org/10.1021/acs.nanolett.9b04452.