Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates
Roman G. Novikov
1, 2
,
Anastasia A Levina
1
,
Denis D Borisov
1
,
Yaroslav V. Tkachev
2
,
Yana B Platonova
4
,
Larisa G. Tomilova
4
,
Publication type: Journal Article
Publication date: 2020-07-16
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The
novel class of gallium catalysts based on cationic gallium
phthalocyanines (RPcGa+) with SbF6– and Sb2F11– weakly coordinating
anions was developed in order to using in the catalytic version for
gallium-specific chemistry. Two cycloaddition/annulation processes
of styrylmalonates with aromatic aldehydes and styrene were implemented
in the catalytic version using this approach. The synthetic strategy
to gallium phthalocyanines and their structural features were studied
in details, including the use of specially adapted 71Ga
NMR spectroscopy in combination with 19F and 121Sb ones, as well as the mechanistic aspects.
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Total citations:
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Citations from 2024:
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GOST
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Novikov R. G. et al. Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates // Organometallics. 2020. Vol. 39. No. 14. pp. 2580-2593.
GOST all authors (up to 50)
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Novikov R. G., Levina A. A., Borisov D. D., Volodin A. D., Korlyukov A., Tkachev Y. V., Platonova Y. B., Tomilova L. G., Tomilov Y. V. Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates // Organometallics. 2020. Vol. 39. No. 14. pp. 2580-2593.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.organomet.0c00113
UR - https://pubs.acs.org/doi/10.1021/acs.organomet.0c00113
TI - Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates
T2 - Organometallics
AU - Novikov, Roman G.
AU - Levina, Anastasia A
AU - Borisov, Denis D
AU - Volodin, Alexander D
AU - Korlyukov, Alexander
AU - Tkachev, Yaroslav V.
AU - Platonova, Yana B
AU - Tomilova, Larisa G.
AU - Tomilov, Yury V.
PY - 2020
DA - 2020/07/16
PB - American Chemical Society (ACS)
SP - 2580-2593
IS - 14
VL - 39
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Novikov,
author = {Roman G. Novikov and Anastasia A Levina and Denis D Borisov and Alexander D Volodin and Alexander Korlyukov and Yaroslav V. Tkachev and Yana B Platonova and Larisa G. Tomilova and Yury V. Tomilov},
title = {Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates},
journal = {Organometallics},
year = {2020},
volume = {39},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/acs.organomet.0c00113},
number = {14},
pages = {2580--2593},
doi = {10.1021/acs.organomet.0c00113}
}
Cite this
MLA
Copy
Novikov, Roman G., et al. “Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates.” Organometallics, vol. 39, no. 14, Jul. 2020, pp. 2580-2593. https://pubs.acs.org/doi/10.1021/acs.organomet.0c00113.