Organometallics

, том 37 , издание 5 , страницы 673-678

A Palladium(II) Complex of a C₄ Chelating Bis(NHC) Diphosphonium Bis(ylide) Ligand

Тип публикации: Journal Article

Дата публикации: 2017-07-19

American Chemical Society (ACS)

Organometallics

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SJR: 0.676

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/acs.organomet.7b00405

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

The preparation and the structure of a palladium(II) complex bearing an extremely electron rich C4 chelating bis(NHC) diphosphonium bis(ylide) ligand are described. This Pd complex is obtained as a single diastereoisomer via a four-step synthesis from the bis(imidazol-1-yl)methane in 43% overall yield. It results from two fully selective processes: the deprotonation of two imidazolium moieties in the presence of phosphonium centers and the coordination of two phosphonium ylides at the metal center. Steric and electrostatic constraints between the triphenylphosphonio substituents at the C-ylidic positions are proposed to explain the diastereoselectivity of the C2 coordination in favor of the dl form (RR/SS).

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Organometallics	Organometallics, 6, 23.08% Organometallics 6 публикаций, 23.08%
European Journal of Inorganic Chemistry	European Journal of Inorganic Chemistry, 3, 11.54% European Journal of Inorganic Chemistry 3 публикации, 11.54%
Inorganic Chemistry	Inorganic Chemistry, 2, 7.69% Inorganic Chemistry 2 публикации, 7.69%
Polyhedron	Polyhedron, 2, 7.69% Polyhedron 2 публикации, 7.69%
Dalton Transactions	Dalton Transactions, 2, 7.69% Dalton Transactions 2 публикации, 7.69%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 3.85% Angewandte Chemie - International Edition 1 публикация, 3.85%
Molecules	Molecules, 1, 3.85% Molecules 1 публикация, 3.85%
Chemistry - An Asian Journal	Chemistry - An Asian Journal, 1, 3.85% Chemistry - An Asian Journal 1 публикация, 3.85%
Angewandte Chemie	Angewandte Chemie, 1, 3.85% Angewandte Chemie 1 публикация, 3.85%
Journal of Organic Chemistry	Journal of Organic Chemistry, 1, 3.85% Journal of Organic Chemistry 1 публикация, 3.85%
Chemical Record	Chemical Record, 1, 3.85% Chemical Record 1 публикация, 3.85%
Chemistry - A European Journal	Chemistry - A European Journal, 1, 3.85% Chemistry - A European Journal 1 публикация, 3.85%
Chemical Communications	Chemical Communications, 1, 3.85% Chemical Communications 1 публикация, 3.85%
Tetrahedron	Tetrahedron, 1, 3.85% Tetrahedron 1 публикация, 3.85%
ACS Sustainable Chemistry and Engineering	ACS Sustainable Chemistry and Engineering, 1, 3.85% ACS Sustainable Chemistry and Engineering 1 публикация, 3.85%
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American Chemical Society (ACS)	American Chemical Society (ACS), 10, 38.46% American Chemical Society (ACS) 10 публикаций, 38.46%
Wiley	Wiley, 8, 30.77% Wiley 8 публикаций, 30.77%
Elsevier	Elsevier, 4, 15.38% Elsevier 4 публикации, 15.38%
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Barthes C. et al. A Palladium(II) Complex of a C4 Chelating Bis(NHC) Diphosphonium Bis(ylide) Ligand // Organometallics. 2017. Vol. 37. No. 5. pp. 673-678.

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Barthes C., Bijani C., Lugan N., Canac Y. A Palladium(II) Complex of a C4 Chelating Bis(NHC) Diphosphonium Bis(ylide) Ligand // Organometallics. 2017. Vol. 37. No. 5. pp. 673-678.

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TY - JOUR

DO - 10.1021/acs.organomet.7b00405

UR - https://doi.org/10.1021/acs.organomet.7b00405

TI - A Palladium(II) Complex of a C4 Chelating Bis(NHC) Diphosphonium Bis(ylide) Ligand

T2 - Organometallics

AU - Barthes, Cécile

AU - Bijani, Christian

AU - Lugan, Noël

AU - Canac, Yves

PY - 2017

DA - 2017/07/19

PB - American Chemical Society (ACS)

SP - 673-678

IS - 5

VL - 37

SN - 0276-7333

SN - 1520-6041

ER -

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@article{2017_Barthes,

author = {Cécile Barthes and Christian Bijani and Noël Lugan and Yves Canac},

title = {A Palladium(II) Complex of a C4 Chelating Bis(NHC) Diphosphonium Bis(ylide) Ligand},

journal = {Organometallics},

year = {2017},

volume = {37},

publisher = {American Chemical Society (ACS)},

month = {jul},

url = {https://doi.org/10.1021/acs.organomet.7b00405},

number = {5},

pages = {673--678},

doi = {10.1021/acs.organomet.7b00405}

}

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Barthes, Cécile, et al. “A Palladium(II) Complex of a C4 Chelating Bis(NHC) Diphosphonium Bis(ylide) Ligand.” Organometallics, vol. 37, no. 5, Jul. 2017, pp. 673-678. https://doi.org/10.1021/acs.organomet.7b00405.