volume 37 issue 3 pages 298-308

Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety

Publication typeJournal Article
Publication date2018-01-17
scimago Q2
wos Q1
SJR0.676
CiteScore5.1
Impact factor2.9
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The selenoether-functionalized imidazolium salt N-[(phenylseleno)methylene)]-N′-methylimidazolium chloride (LH+Cl–) was transformed into the metal–carbene complexes [AgCl(L)], [AuCl(L)], [PdCl2(L)], and [PtCl2(L)] by the reaction with Ag2O and an additional transmetalation reaction of [AgCl(L)] with [(THT)AuCl], [(COD)PdCl2], and [(COD)PtCl2], respectively (THT = tetrahydrothiophene, COD = cyclooctadiene). The compound [AuI2Cl(L)] was prepared by oxidation of [AuCl(L)] with elemental iodine. The microwave-assisted decomposition of [PdCl2(L)] in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIm]NTf2) or in propylene carbonate led to the formation of Pd17Se15 nanoparticles of 51 ± 17 or 26 ± 7 nm diameter, respectively. The decomposition of the platinum complex resulted in either small Pt clusters around 1 nm size from the ionic liquid suspension or Pt nanoparticles of 3 ± 1 nm diameter in propylene carbonate. High-resolution X-ray photoelectron spectroscopy (HR-XPS) and ...
Found 
Found 

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GOST Copy
Klauke K. et al. Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety // Organometallics. 2018. Vol. 37. No. 3. pp. 298-308.
GOST all authors (up to 50) Copy
Klauke K., Gruber I., Knedel T. O., Schmolke L., Barthel J., Breitzke H., Buntkowsky G., Janiak C. Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety // Organometallics. 2018. Vol. 37. No. 3. pp. 298-308.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.organomet.7b00678
UR - https://doi.org/10.1021/acs.organomet.7b00678
TI - Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety
T2 - Organometallics
AU - Klauke, Karsten
AU - Gruber, Irina
AU - Knedel, Tim Oliver
AU - Schmolke, Laura
AU - Barthel, Juri
AU - Breitzke, Hergen
AU - Buntkowsky, Gerd
AU - Janiak, Christoph
PY - 2018
DA - 2018/01/17
PB - American Chemical Society (ACS)
SP - 298-308
IS - 3
VL - 37
SN - 0276-7333
SN - 1520-6041
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Klauke,
author = {Karsten Klauke and Irina Gruber and Tim Oliver Knedel and Laura Schmolke and Juri Barthel and Hergen Breitzke and Gerd Buntkowsky and Christoph Janiak},
title = {Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety},
journal = {Organometallics},
year = {2018},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.organomet.7b00678},
number = {3},
pages = {298--308},
doi = {10.1021/acs.organomet.7b00678}
}
MLA
Cite this
MLA Copy
Klauke, Karsten, et al. “Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety.” Organometallics, vol. 37, no. 3, Jan. 2018, pp. 298-308. https://doi.org/10.1021/acs.organomet.7b00678.