Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands
Publication type: Journal Article
Publication date: 2018-02-08
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
New air-stable tripodal triphosphine ligands 1,8,13-tris(diisopropylphosphino)-2,3-dimethoxytriptycene (P3T1) and 1,8,13-tris(diphenylphosphino)-2,3-dimethoxytriptycene (P3T2) are presented and discussed. Their synthesis is based on the first practical synthesis of 1,8,13-tribromotriptycene. Reaction with palladium leads to the formation of new pseudo-C3-symmetric carbometalated complexes: namely, Pd(P3T1)Cl and Pd(P3T2)Cl. The catalytic activity of the new ligands and complexes was tested in the palladium-catalyzed chemoselective transfer hydrogenation of α,β-unsaturated ketones.
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Total citations:
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Citations from 2025:
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GOST
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Kisets I., Gelman D. Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands // Organometallics. 2018. Vol. 37. No. 4. pp. 526-529.
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Kisets I., Gelman D. Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands // Organometallics. 2018. Vol. 37. No. 4. pp. 526-529.
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RIS
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TY - JOUR
DO - 10.1021/acs.organomet.7b00907
UR - https://doi.org/10.1021/acs.organomet.7b00907
TI - Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands
T2 - Organometallics
AU - Kisets, Ilya
AU - Gelman, Dmitri
PY - 2018
DA - 2018/02/08
PB - American Chemical Society (ACS)
SP - 526-529
IS - 4
VL - 37
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Kisets,
author = {Ilya Kisets and Dmitri Gelman},
title = {Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands},
journal = {Organometallics},
year = {2018},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.organomet.7b00907},
number = {4},
pages = {526--529},
doi = {10.1021/acs.organomet.7b00907}
}
Cite this
MLA
Copy
Kisets, Ilya, and Dmitri Gelman. “Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands.” Organometallics, vol. 37, no. 4, Feb. 2018, pp. 526-529. https://doi.org/10.1021/acs.organomet.7b00907.
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