Organometallics

, том 37 , издание 4 , страницы 526-529

Carbometalated Complexes Possessing Tripodal Pseudo-C₃-Symmetric Triptycene-Based Ligands

Ilya Kisets ¹

Dmitri Gelman ¹

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Institute of Chemistry, Edmond J. Safra Campus, The Hebrew University of Jerusalem, Jerusalem 91904, Israel |

Тип публикации: Journal Article

Дата публикации: 2018-02-08

American Chemical Society (ACS)

Organometallics

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SJR: 0.676

CiteScore: 5.1

Impact factor: 2.9

ISSN: 02767333, 15206041

DOI: 10.1021/acs.organomet.7b00907

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Organic Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

New air-stable tripodal triphosphine ligands 1,8,13-tris(diisopropylphosphino)-2,3-dimethoxytriptycene (P3T1) and 1,8,13-tris(diphenylphosphino)-2,3-dimethoxytriptycene (P3T2) are presented and discussed. Their synthesis is based on the first practical synthesis of 1,8,13-tribromotriptycene. Reaction with palladium leads to the formation of new pseudo-C3-symmetric carbometalated complexes: namely, Pd(P3T1)Cl and Pd(P3T2)Cl. The catalytic activity of the new ligands and complexes was tested in the palladium-catalyzed chemoselective transfer hydrogenation of α,β-unsaturated ketones.

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Kisets I., Gelman D. Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands // Organometallics. 2018. Vol. 37. No. 4. pp. 526-529.

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Kisets I., Gelman D. Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands // Organometallics. 2018. Vol. 37. No. 4. pp. 526-529.

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TY - JOUR

DO - 10.1021/acs.organomet.7b00907

UR - https://doi.org/10.1021/acs.organomet.7b00907

TI - Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands

T2 - Organometallics

AU - Kisets, Ilya

AU - Gelman, Dmitri

PY - 2018

DA - 2018/02/08

PB - American Chemical Society (ACS)

SP - 526-529

IS - 4

VL - 37

SN - 0276-7333

SN - 1520-6041

ER -

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@article{2018_Kisets,

author = {Ilya Kisets and Dmitri Gelman},

title = {Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands},

journal = {Organometallics},

year = {2018},

volume = {37},

publisher = {American Chemical Society (ACS)},

month = {feb},

url = {https://doi.org/10.1021/acs.organomet.7b00907},

number = {4},

pages = {526--529},

doi = {10.1021/acs.organomet.7b00907}

}

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Kisets, Ilya, and Dmitri Gelman. “Carbometalated Complexes Possessing Tripodal Pseudo-C3-Symmetric Triptycene-Based Ligands.” Organometallics, vol. 37, no. 4, Feb. 2018, pp. 526-529. https://doi.org/10.1021/acs.organomet.7b00907.