volume 38 issue 19 pages 3796-3803

Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction

Publication typeJournal Article
Publication date2019-09-26
scimago Q2
wos Q1
SJR0.676
CiteScore5.1
Impact factor2.9
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We report the synthesis of unsaturated silacycles via an intramolecular silyl-Heck reaction. Using palladium catalysis, silicon electrophiles tethered to alkenes cyclize to form 5- and 6-membered silicon heterocycles. The effects of alkene substitution and tether length on the efficiency and regioselectivity of the cyclizations are described. Finally, through the use of an intramolecular tether, the first examples of disubstituted alkenes in silyl-Heck reactions are reported.
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GOST Copy
Reid W. B., Mcatee J. R., WATSON D. P. Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction // Organometallics. 2019. Vol. 38. No. 19. pp. 3796-3803.
GOST all authors (up to 50) Copy
Reid W. B., Mcatee J. R., WATSON D. P. Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction // Organometallics. 2019. Vol. 38. No. 19. pp. 3796-3803.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.organomet.9b00498
UR - https://doi.org/10.1021/acs.organomet.9b00498
TI - Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction
T2 - Organometallics
AU - Reid, William B
AU - Mcatee, Jesse R
AU - WATSON, DONALD P.
PY - 2019
DA - 2019/09/26
PB - American Chemical Society (ACS)
SP - 3796-3803
IS - 19
VL - 38
PMID - 32431470
SN - 0276-7333
SN - 1520-6041
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Reid,
author = {William B Reid and Jesse R Mcatee and DONALD P. WATSON},
title = {Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction},
journal = {Organometallics},
year = {2019},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.organomet.9b00498},
number = {19},
pages = {3796--3803},
doi = {10.1021/acs.organomet.9b00498}
}
MLA
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MLA Copy
Reid, William B., et al. “Synthesis of Unsaturated Silyl Heterocycles via an Intramolecular Silyl-Heck Reaction.” Organometallics, vol. 38, no. 19, Sep. 2019, pp. 3796-3803. https://doi.org/10.1021/acs.organomet.9b00498.