volume 38 issue 22 pages 4479-4484

Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-Benzenes

Alen Bjelopetrović 1
Marko Robić 1
Ivan Halasz 1
Davorin Babić 1
Monika Kulcsar 1
Manda Ćurić 1
Publication typeJournal Article
Publication date2019-11-13
scimago Q2
wos Q1
SJR0.676
CiteScore5.1
Impact factor2.9
ISSN02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The solvent-free ball-milling method for substitution of anionic ligands in organopalladium compounds was developed. Reactions of acetate, acetylacetonate, chloride, or tetrafluoroborate of mono- or dicyclopalladated azobenzenes with alkali salts of chloride, acetate and acetylacetonate yielded target products, some of which could not be obtained via direct C–H bond activation by Pd(II) precursors. The formation of products was monitored in situ by Raman spectroscopy and ex situ by NMR and IR spectroscopies and PXRD. The reported solid-state pathway provides easy access to organopalladium derivatives in high yields and in shorter reaction times than solvent-based protocols.
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Bjelopetrović A. et al. Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-Benzenes // Organometallics. 2019. Vol. 38. No. 22. pp. 4479-4484.
GOST all authors (up to 50) Copy
Bjelopetrović A., Robić M., Halasz I., Babić D., Kulcsar M., Ćurić M. Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-Benzenes // Organometallics. 2019. Vol. 38. No. 22. pp. 4479-4484.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.organomet.9b00626
UR - https://doi.org/10.1021/acs.organomet.9b00626
TI - Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-Benzenes
T2 - Organometallics
AU - Bjelopetrović, Alen
AU - Robić, Marko
AU - Halasz, Ivan
AU - Babić, Davorin
AU - Kulcsar, Monika
AU - Ćurić, Manda
PY - 2019
DA - 2019/11/13
PB - American Chemical Society (ACS)
SP - 4479-4484
IS - 22
VL - 38
SN - 0276-7333
SN - 1520-6041
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Bjelopetrović,
author = {Alen Bjelopetrović and Marko Robić and Ivan Halasz and Davorin Babić and Monika Kulcsar and Manda Ćurić},
title = {Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-Benzenes},
journal = {Organometallics},
year = {2019},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.organomet.9b00626},
number = {22},
pages = {4479--4484},
doi = {10.1021/acs.organomet.9b00626}
}
MLA
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Bjelopetrović, Alen, et al. “Facile Mechanochemical Anion Substitution in Cyclopalladated Azo-Benzenes.” Organometallics, vol. 38, no. 22, Nov. 2019, pp. 4479-4484. https://doi.org/10.1021/acs.organomet.9b00626.