Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity
Publication type: Journal Article
Publication date: 2020-03-06
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
32141761
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A highly selective and convenient Ru(II)-catalyzed C-H bond activation protocol has been demonstrated to access 4-alkynylated isoquinolines, which was so far elusive from 1,3-diynes. Subsequently, the same protocol was extended to furnish various 4-4'-biisoquinoline motifs. The key feature of this work is the regioselective disparity observed during the migratory insertion of an organoruthenium metallacycle with the C3-C4 triple bond of 1,3-diynes resulting in divergent products as compared to the existing literature.
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56
Total citations:
56
Citations from 2025:
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(10.71%)
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Kumar S., Nair A. M., Volla C. M. R. Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity // Organic Letters. 2020. Vol. 22. No. 6. pp. 2141-2146.
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Kumar S., Nair A. M., Volla C. M. R. Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity // Organic Letters. 2020. Vol. 22. No. 6. pp. 2141-2146.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.0c00120
UR - https://doi.org/10.1021/acs.orglett.0c00120
TI - Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity
T2 - Organic Letters
AU - Kumar, Shreemoyee
AU - Nair, Akshay M.
AU - Volla, Chandra M. R.
PY - 2020
DA - 2020/03/06
PB - American Chemical Society (ACS)
SP - 2141-2146
IS - 6
VL - 22
PMID - 32141761
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Kumar,
author = {Shreemoyee Kumar and Akshay M. Nair and Chandra M. R. Volla},
title = {Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.orglett.0c00120},
number = {6},
pages = {2141--2146},
doi = {10.1021/acs.orglett.0c00120}
}
Cite this
MLA
Copy
Kumar, Shreemoyee, et al. “Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity.” Organic Letters, vol. 22, no. 6, Mar. 2020, pp. 2141-2146. https://doi.org/10.1021/acs.orglett.0c00120.