, volume 22 , issue 16 , pages 6388-6393

Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates

Liyan Fu ¹

Qiang Chen ¹

Yoshihiro NISHIHARA ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Graduate school of natural science and technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan |

Research Institute for Interdisciplinary Science, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan |

Publication type: Journal Article

Publication date: 2020-08-01

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.0c02215

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PubMed ID: 32806213

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

We report the transition metal-free decarboxylative cross-coupling reactions of acyl fluorides with potassium perfluorobenzoates. Compared with traditional transition metal-catalyzed cross-couplings, this protocol presents an extremely environmentally benign pathway to afford unsymmetrical diaryl ketones. To install perfluorophenyl groups, this method highlights highly selective, inexpensive, and nontoxic conditions. The reaction system tolerates various functional groups in acyl fluorides. Remarkably, all of the starting materials can be prepared from abundant carboxylic acids and the reaction proceeds without any catalysts and additives.

Found

1 citation

Shchegolkov Evgeny

70 publications, 927 citations, 57 reviews

h-index: 16

Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Research interests

Organic synthesis

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Fu L., Chen Q., NISHIHARA Y. Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates // Organic Letters. 2020. Vol. 22. No. 16. pp. 6388-6393.

GOST all authors (up to 50) Copy

Fu L., Chen Q., NISHIHARA Y. Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates // Organic Letters. 2020. Vol. 22. No. 16. pp. 6388-6393.

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RIS Copy

TY - JOUR

DO - 10.1021/acs.orglett.0c02215

UR - https://doi.org/10.1021/acs.orglett.0c02215

TI - Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates

T2 - Organic Letters

AU - Fu, Liyan

AU - Chen, Qiang

AU - NISHIHARA, Yoshihiro

PY - 2020

DA - 2020/08/01

PB - American Chemical Society (ACS)

SP - 6388-6393

IS - 16

VL - 22

PMID - 32806213

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2020_Fu,

author = {Liyan Fu and Qiang Chen and Yoshihiro NISHIHARA},

title = {Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates},

journal = {Organic Letters},

year = {2020},

volume = {22},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/acs.orglett.0c02215},

number = {16},

pages = {6388--6393},

doi = {10.1021/acs.orglett.0c02215}

}

MLA

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MLA Copy

Fu, Liyan, et al. “Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates.” Organic Letters, vol. 22, no. 16, Aug. 2020, pp. 6388-6393. https://doi.org/10.1021/acs.orglett.0c02215.

Publisher

American Chemical Society (ACS)

Journal

Organic Letters

scimago Q1

wos Q1

SJR

1.235

CiteScore

8.7

Impact factor

5.0

ISSN

15237060 (Print)

15237052 (Electronic)