Organic Letters, volume 22, issue 16, pages 6388-6393

Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates

Liyan Fu ¹

Qiang Chen ¹

Yoshihiro NISHIHARA ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Graduate school of natural science and technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan |

Research Institute for Interdisciplinary Science, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan |

Publication type: Journal Article

Publication date: 2020-08-01

American Chemical Society (ACS)

Journal: Organic Letters

Quartile SCImago

Quartile WOS

SJR: 1.245

CiteScore: 9.3

Impact factor: 4.9

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.0c02215

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Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

We report the transition metal-free decarboxylative cross-coupling reactions of acyl fluorides with potassium perfluorobenzoates. Compared with traditional transition metal-catalyzed cross-couplings, this protocol presents an extremely environmentally benign pathway to afford unsymmetrical diaryl ketones. To install perfluorophenyl groups, this method highlights highly selective, inexpensive, and nontoxic conditions. The reaction system tolerates various functional groups in acyl fluorides. Remarkably, all of the starting materials can be prepared from abundant carboxylic acids and the reaction proceeds without any catalysts and additives.

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Fu L., Chen Q., NISHIHARA Y. Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates // Organic Letters. 2020. Vol. 22. No. 16. pp. 6388-6393.

GOST all authors (up to 50) Copy

Fu L., Chen Q., NISHIHARA Y. Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates // Organic Letters. 2020. Vol. 22. No. 16. pp. 6388-6393.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.orglett.0c02215

UR - https://doi.org/10.1021/acs.orglett.0c02215

TI - Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates

T2 - Organic Letters

AU - Fu, Liyan

AU - NISHIHARA, Yoshihiro

AU - Chen, Qiang

PY - 2020

DA - 2020/08/01

PB - American Chemical Society (ACS)

SP - 6388-6393

IS - 16

VL - 22

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

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BibTex Copy

@article{2020_Fu,

author = {Liyan Fu and Yoshihiro NISHIHARA and Qiang Chen},

title = {Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates},

journal = {Organic Letters},

year = {2020},

volume = {22},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/acs.orglett.0c02215},

number = {16},

pages = {6388--6393},

doi = {10.1021/acs.orglett.0c02215}

}

MLA

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MLA Copy

Fu, Liyan, et al. “Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates.” Organic Letters, vol. 22, no. 16, Aug. 2020, pp. 6388-6393. https://doi.org/10.1021/acs.orglett.0c02215.

Found error?

Publisher

American Chemical Society (ACS)

Journal

Organic Letters

Quartile SCImago

Quartile WOS

SJR

1.245

CiteScore

9.3

Impact factor

4.9

ISSN

15237060 (Print)

15237052 (Electronic)