Organic Letters, volume 23, issue 11, pages 4337-4341
Rhodium-Catalyzed Dehydrogenative Cycloisomerization of Dienylcyclopropane to Highly Substituted Toluene
Publication type: Journal Article
Publication date: 2021-05-24
Journal:
Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A rhodium-catalyzed dehydrogenative cycloisomerization of dienylcyclopropane compounds is reported, which provides a straightforward approach to a variety of highly substituted toluene derivatives in 67-85% yields. The dienylcyclopropane-imides are produced by a single-step formal three-component olefination procedure. Preliminary mechanistic studies indicated that an electron-withdrawing group as R plays a critical role in completing this transformation.
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Organic Letters
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Russian Chemical Reviews
1 publication, 50%
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Citations by publishers
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American Chemical Society (ACS)
1 publication, 50%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 50%
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Nie W., Shen S., Ma C. Rhodium-Catalyzed Dehydrogenative Cycloisomerization of Dienylcyclopropane to Highly Substituted Toluene // Organic Letters. 2021. Vol. 23. No. 11. pp. 4337-4341.
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Nie W., Shen S., Ma C. Rhodium-Catalyzed Dehydrogenative Cycloisomerization of Dienylcyclopropane to Highly Substituted Toluene // Organic Letters. 2021. Vol. 23. No. 11. pp. 4337-4341.
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TY - JOUR
DO - 10.1021/acs.orglett.1c01265
UR - https://doi.org/10.1021/acs.orglett.1c01265
TI - Rhodium-Catalyzed Dehydrogenative Cycloisomerization of Dienylcyclopropane to Highly Substituted Toluene
T2 - Organic Letters
AU - Nie, Wo
AU - Shen, Shichao
AU - Ma, Cheng
PY - 2021
DA - 2021/05/24 00:00:00
PB - American Chemical Society (ACS)
SP - 4337-4341
IS - 11
VL - 23
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2021_Nie,
author = {Wo Nie and Shichao Shen and Cheng Ma},
title = {Rhodium-Catalyzed Dehydrogenative Cycloisomerization of Dienylcyclopropane to Highly Substituted Toluene},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.orglett.1c01265},
number = {11},
pages = {4337--4341},
doi = {10.1021/acs.orglett.1c01265}
}
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Nie, Wo, et al. “Rhodium-Catalyzed Dehydrogenative Cycloisomerization of Dienylcyclopropane to Highly Substituted Toluene.” Organic Letters, vol. 23, no. 11, May. 2021, pp. 4337-4341. https://doi.org/10.1021/acs.orglett.1c01265.