Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates
Publication type: Journal Article
Publication date: 2021-06-14
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
34124913
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The electrochemical synthesis of fluorinated ketones from enol acetates and RfSO2Na in an undivided cell under constant current conditions was developed. The electrosynthesis proceeded via perfluoroalkyl radical generation from sodium perfluoroalkyl sulfinate followed by addition to the enol acetate and transformation of the resulting C radical to a fluorinated ketone. The method is applicable to a wide range of enol acetates and results in the desired products in yields of 20 to 85%.
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Metrics
35
Total citations:
35
Citations from 2024:
16
(45%)
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MLA
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GOST
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Vil’ V. A. et al. Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates // Organic Letters. 2021. Vol. 23. No. 13. pp. 5107-5112.
GOST all authors (up to 50)
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Vil’ V. A., Merkulova V. M., Ilovaisky A. I., Paveliev S. A., Nikishin G. I., Terent'ev A. O. Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates // Organic Letters. 2021. Vol. 23. No. 13. pp. 5107-5112.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c01643
UR - https://doi.org/10.1021/acs.orglett.1c01643
TI - Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates
T2 - Organic Letters
AU - Vil’, Vera A.
AU - Merkulova, Valentina M
AU - Ilovaisky, Alexey I
AU - Paveliev, Stanislav A
AU - Nikishin, Gennady I.
AU - Terent'ev, Alexander O.
PY - 2021
DA - 2021/06/14
PB - American Chemical Society (ACS)
SP - 5107-5112
IS - 13
VL - 23
PMID - 34124913
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Vil’,
author = {Vera A. Vil’ and Valentina M Merkulova and Alexey I Ilovaisky and Stanislav A Paveliev and Gennady I. Nikishin and Alexander O. Terent'ev},
title = {Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.orglett.1c01643},
number = {13},
pages = {5107--5112},
doi = {10.1021/acs.orglett.1c01643}
}
Cite this
MLA
Copy
Vil’, Vera A., et al. “Electrochemical Synthesis of Fluorinated Ketones from Enol Acetates and Sodium Perfluoroalkyl Sulfinates.” Organic Letters, vol. 23, no. 13, Jun. 2021, pp. 5107-5112. https://doi.org/10.1021/acs.orglett.1c01643.