Organic Letters

, volume 23 , issue 16 , pages 6488-6493

Convergent Paired Electrochemical Synthesis of Azoxy and Azo Compounds: An Insight into the Reaction Mechanism

Ali Sadatnabi ¹

Niloofar Mohamadighader ¹

Davood Nematollahi ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Faculty of Chemistry, Bu-Ali-Sina University, P.O. Box 65174, Hamedan, Iran |

Publication type: Journal Article

Publication date: 2021-08-04

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.1c02304

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PubMed ID: 34347493

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

A convergent paired electrochemical method was developed for the synthesis of azoxy and azo compounds starting from the corresponding nitroarenes. We propose a unique mechanism for electrosynthesis of azoxy and azo compounds. We find that both anodic and cathodic reactions are responsible for the synthesis of these compounds. The synthesis of azoxy and azo derivatives have been successfully performed in an undivided cell, using carbon rod electrodes, by constant current electrolysis at room temperature.

Found

1 citation

Krylov Igor

PhD in Chemistry

82 publications, 1 939 citations, 19 reviews

h-index: 26

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Green chemistry

Organic Chemistry

Organic electrochemistry

Organic synthesis

Photochemistry

Plant protection

1 citation

Leonov Nikita

🥼 🤝

19 publications, 157 citations

h-index: 7

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Dvinyaninova Tatyyana

1 publication, 4 citations

h-index: 1

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Mendeleev University of Chemical Technology of Russia

Research interests

Chemistry of nitrogen-containing heterocycles

Organic Chemistry

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Sadatnabi A., Mohamadighader N., Nematollahi D. Convergent Paired Electrochemical Synthesis of Azoxy and Azo Compounds: An Insight into the Reaction Mechanism // Organic Letters. 2021. Vol. 23. No. 16. pp. 6488-6493.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.orglett.1c02304

UR - https://doi.org/10.1021/acs.orglett.1c02304

TI - Convergent Paired Electrochemical Synthesis of Azoxy and Azo Compounds: An Insight into the Reaction Mechanism

T2 - Organic Letters

AU - Sadatnabi, Ali

AU - Mohamadighader, Niloofar

AU - Nematollahi, Davood

PY - 2021

DA - 2021/08/04

PB - American Chemical Society (ACS)

SP - 6488-6493

IS - 16

VL - 23

PMID - 34347493

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2021_Sadatnabi,

author = {Ali Sadatnabi and Niloofar Mohamadighader and Davood Nematollahi},

title = {Convergent Paired Electrochemical Synthesis of Azoxy and Azo Compounds: An Insight into the Reaction Mechanism},

journal = {Organic Letters},

year = {2021},

volume = {23},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/acs.orglett.1c02304},

number = {16},

pages = {6488--6493},

doi = {10.1021/acs.orglett.1c02304}

}

MLA

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MLA Copy

Sadatnabi, Ali, et al. “Convergent Paired Electrochemical Synthesis of Azoxy and Azo Compounds: An Insight into the Reaction Mechanism.” Organic Letters, vol. 23, no. 16, Aug. 2021, pp. 6488-6493. https://doi.org/10.1021/acs.orglett.1c02304.

Publisher

American Chemical Society (ACS)

Journal

Organic Letters

scimago Q1

wos Q1

SJR

1.235

CiteScore

8.7

Impact factor

5.0

ISSN

15237060 (Print)

15237052 (Electronic)