Palladium-Catalyzed Silylation of 2,3-Allenols with Unactivated Disilanes: Access to 2-Silyl-1,3-butadienes and α-Silyl-β-hydroxy Vinylsilanes
Guang-Li Xu
1
,
Zhong-Xia Wang
1, 2
Publication type: Journal Article
Publication date: 2022-01-04
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
35057630
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Regioselective silylation of 2,3-allenols with disilanes was carried out under catalysis of Pd2dba3/P(o-MeOC6H4)3. In the presence of Cs2CO3, the reaction achieved 2-silyl-1,3-dienes. Reaction of 1-aryl-2,3-allenols gave the products with excellent Z/E selectivity and E-isomers as the major species. Reaction of α-alkylallenols or α-alkyl-α-aryl-allenols resulted in products with moderate Z/E selectivity and E-isomers are also major. Without a base, the reaction produced α-silyl-β-hydroxyl vinylsilanes, which were converted to 2-silyl-1,3-dienes upon treatment with Cs2CO3.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
ACS Catalysis
2 publications, 20%
|
|
|
Organic Letters
2 publications, 20%
|
|
|
Advanced Synthesis and Catalysis
1 publication, 10%
|
|
|
Organic and Biomolecular Chemistry
1 publication, 10%
|
|
|
Chemistry - An Asian Journal
1 publication, 10%
|
|
|
Angewandte Chemie
1 publication, 10%
|
|
|
Angewandte Chemie - International Edition
1 publication, 10%
|
|
|
Russian Chemical Reviews
1 publication, 10%
|
|
|
1
2
|
Publishers
|
1
2
3
4
|
|
|
American Chemical Society (ACS)
4 publications, 40%
|
|
|
Wiley
4 publications, 40%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 10%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 10%
|
|
|
1
2
3
4
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
10
Total citations:
10
Citations from 2024:
5
(50%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Xu G., Wang Z. Palladium-Catalyzed Silylation of 2,3-Allenols with Unactivated Disilanes: Access to 2-Silyl-1,3-butadienes and α-Silyl-β-hydroxy Vinylsilanes // Organic Letters. 2022. Vol. 24. No. 2. pp. 692-696.
GOST all authors (up to 50)
Copy
Xu G., Wang Z. Palladium-Catalyzed Silylation of 2,3-Allenols with Unactivated Disilanes: Access to 2-Silyl-1,3-butadienes and α-Silyl-β-hydroxy Vinylsilanes // Organic Letters. 2022. Vol. 24. No. 2. pp. 692-696.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c04141
UR - https://doi.org/10.1021/acs.orglett.1c04141
TI - Palladium-Catalyzed Silylation of 2,3-Allenols with Unactivated Disilanes: Access to 2-Silyl-1,3-butadienes and α-Silyl-β-hydroxy Vinylsilanes
T2 - Organic Letters
AU - Xu, Guang-Li
AU - Wang, Zhong-Xia
PY - 2022
DA - 2022/01/04
PB - American Chemical Society (ACS)
SP - 692-696
IS - 2
VL - 24
PMID - 35057630
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Xu,
author = {Guang-Li Xu and Zhong-Xia Wang},
title = {Palladium-Catalyzed Silylation of 2,3-Allenols with Unactivated Disilanes: Access to 2-Silyl-1,3-butadienes and α-Silyl-β-hydroxy Vinylsilanes},
journal = {Organic Letters},
year = {2022},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.orglett.1c04141},
number = {2},
pages = {692--696},
doi = {10.1021/acs.orglett.1c04141}
}
Cite this
MLA
Copy
Xu, Guang-Li, et al. “Palladium-Catalyzed Silylation of 2,3-Allenols with Unactivated Disilanes: Access to 2-Silyl-1,3-butadienes and α-Silyl-β-hydroxy Vinylsilanes.” Organic Letters, vol. 24, no. 2, Jan. 2022, pp. 692-696. https://doi.org/10.1021/acs.orglett.1c04141.