Organic Letters, volume 24, issue 11, pages 2220-2225
Synthesis of Trisubstituted Furans via Copper(I)-Catalyzed Strain-Driving Cycloisomerization/Annulative Fragmentation
Publication type: Journal Article
Publication date: 2022-03-14
Journal:
Organic Letters
Q1
Q1
SJR: 1.245
CiteScore: 9.3
Impact factor: 4.9
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The in situ formed furan-fused cyclobutenes via Cu(I)-catalyzed cycloisomerization of readily available allenyl ketones bearing a cyclopropyl moiety are a highly reactive and powerful species, which undergo annulative fragmentation with terminal ynones to afford a wide variety of functional furans in moderate to high yields. This ring-distortion protocol features an unprecedented strain-controlled cycloisomerization/Diels-Alder/retro-Diels-Alder (CDRD) sequence under mild conditions.
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Xie R. et al. Synthesis of Trisubstituted Furans via Copper(I)-Catalyzed Strain-Driving Cycloisomerization/Annulative Fragmentation // Organic Letters. 2022. Vol. 24. No. 11. pp. 2220-2225.
GOST all authors (up to 50)
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Xie R., Zhao Z., Zhao Y., Li R., Yao J., Miao M. Synthesis of Trisubstituted Furans via Copper(I)-Catalyzed Strain-Driving Cycloisomerization/Annulative Fragmentation // Organic Letters. 2022. Vol. 24. No. 11. pp. 2220-2225.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.2c00578
UR - https://doi.org/10.1021/acs.orglett.2c00578
TI - Synthesis of Trisubstituted Furans via Copper(I)-Catalyzed Strain-Driving Cycloisomerization/Annulative Fragmentation
T2 - Organic Letters
AU - Xie, Ruyu
AU - Zhao, Zhiqiang
AU - Zhao, Yongxing
AU - Li, Rui
AU - Yao, Jinzhong
AU - Miao, Maozhong
PY - 2022
DA - 2022/03/14
PB - American Chemical Society (ACS)
SP - 2220-2225
IS - 11
VL - 24
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Xie,
author = {Ruyu Xie and Zhiqiang Zhao and Yongxing Zhao and Rui Li and Jinzhong Yao and Maozhong Miao},
title = {Synthesis of Trisubstituted Furans via Copper(I)-Catalyzed Strain-Driving Cycloisomerization/Annulative Fragmentation},
journal = {Organic Letters},
year = {2022},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.orglett.2c00578},
number = {11},
pages = {2220--2225},
doi = {10.1021/acs.orglett.2c00578}
}
Cite this
MLA
Copy
Xie, Ruyu, et al. “Synthesis of Trisubstituted Furans via Copper(I)-Catalyzed Strain-Driving Cycloisomerization/Annulative Fragmentation.” Organic Letters, vol. 24, no. 11, Mar. 2022, pp. 2220-2225. https://doi.org/10.1021/acs.orglett.2c00578.