Diverse Synthesis of Alkenylsilanes via Pd-Catalyzed Alkenyl C–H Silylation
Zi-Hang Ye
1, 2
,
Fei Hu Gou
2
,
Fei-Hu Gou
2
,
Yichen Wu
2
,
Chuan Ying Li
1
,
Chuanying Li
1
,
Peng Wang
2, 3, 4
Publication type: Journal Article
Publication date: 2023-03-15
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
36921249
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Here, we disclose a general approach for the diverse synthesis of alkenylsilanes in a highly efficient, stereoselective, and atom-economic manner by leveraging the palladium-catalyzed disilylation reaction of 2-bromostyrene derivatives with hexamethyldisilane, which is suitable for the preparation of a series of disubstituted, trisubstituted, and tetrasubstituted alkenylsilanes. Furthermore, the resulting tetrasubstituted alkenylsilanes could be readily transformed into the corresponding diarylated benzosiloles, which have been proven to be a potential AIE material and a fluorene material.
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16
Total citations:
16
Citations from 2024:
13
(81.25%)
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MLA
Cite this
GOST
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Ye Z. et al. Diverse Synthesis of Alkenylsilanes via Pd-Catalyzed Alkenyl C–H Silylation // Organic Letters. 2023. Vol. 25. No. 12. pp. 2145-2150.
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Ye Z., Gou F. H., Gou F., Wu Y., Li C. Y., Li C., Wang P. Diverse Synthesis of Alkenylsilanes via Pd-Catalyzed Alkenyl C–H Silylation // Organic Letters. 2023. Vol. 25. No. 12. pp. 2145-2150.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.3c00633
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c00633
TI - Diverse Synthesis of Alkenylsilanes via Pd-Catalyzed Alkenyl C–H Silylation
T2 - Organic Letters
AU - Ye, Zi-Hang
AU - Gou, Fei Hu
AU - Gou, Fei-Hu
AU - Wu, Yichen
AU - Li, Chuan Ying
AU - Li, Chuanying
AU - Wang, Peng
PY - 2023
DA - 2023/03/15
PB - American Chemical Society (ACS)
SP - 2145-2150
IS - 12
VL - 25
PMID - 36921249
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2023_Ye,
author = {Zi-Hang Ye and Fei Hu Gou and Fei-Hu Gou and Yichen Wu and Chuan Ying Li and Chuanying Li and Peng Wang},
title = {Diverse Synthesis of Alkenylsilanes via Pd-Catalyzed Alkenyl C–H Silylation},
journal = {Organic Letters},
year = {2023},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c00633},
number = {12},
pages = {2145--2150},
doi = {10.1021/acs.orglett.3c00633}
}
Cite this
MLA
Copy
Ye, Zi-Hang, et al. “Diverse Synthesis of Alkenylsilanes via Pd-Catalyzed Alkenyl C–H Silylation.” Organic Letters, vol. 25, no. 12, Mar. 2023, pp. 2145-2150. https://pubs.acs.org/doi/10.1021/acs.orglett.3c00633.
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