Palladium-Catalyzed Stereoselective Defluorosilylation of gem-Difluoroalkenes for the Synthesis of Tetrasubstituted Monofluorinated Vinylsilanes
Publication type: Journal Article
Publication date: 2023-03-30
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
36995018
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Stereoselective synthesis of tetrasubstituted vinylsilanes is a challenging task. We herein report a novel palladium(0)-catalyzed defluorosilylation of β,β-difluoroacrylates to access tetrasubstituted vinylsilanes containing the monofluoroalkene motif in excellent diastereoselectivities (>99:1). This is our first example of C-heteroatom bond formation from the C-F bond under such a Pd catalytic manifold.
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16
Total citations:
16
Citations from 2024:
13
(81.25%)
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GOST
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Zong Y., Luo Z., Tsui G. C. Palladium-Catalyzed Stereoselective Defluorosilylation of gem-Difluoroalkenes for the Synthesis of Tetrasubstituted Monofluorinated Vinylsilanes // Organic Letters. 2023. Vol. 25. No. 13. pp. 2333-2337.
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Zong Y., Luo Z., Tsui G. C. Palladium-Catalyzed Stereoselective Defluorosilylation of gem-Difluoroalkenes for the Synthesis of Tetrasubstituted Monofluorinated Vinylsilanes // Organic Letters. 2023. Vol. 25. No. 13. pp. 2333-2337.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.3c00718
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c00718
TI - Palladium-Catalyzed Stereoselective Defluorosilylation of gem-Difluoroalkenes for the Synthesis of Tetrasubstituted Monofluorinated Vinylsilanes
T2 - Organic Letters
AU - Zong, Yuwei
AU - Luo, Ziwei
AU - Tsui, Gavin Chit
PY - 2023
DA - 2023/03/30
PB - American Chemical Society (ACS)
SP - 2333-2337
IS - 13
VL - 25
PMID - 36995018
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2023_Zong,
author = {Yuwei Zong and Ziwei Luo and Gavin Chit Tsui},
title = {Palladium-Catalyzed Stereoselective Defluorosilylation of gem-Difluoroalkenes for the Synthesis of Tetrasubstituted Monofluorinated Vinylsilanes},
journal = {Organic Letters},
year = {2023},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c00718},
number = {13},
pages = {2333--2337},
doi = {10.1021/acs.orglett.3c00718}
}
Cite this
MLA
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Zong, Yuwei, et al. “Palladium-Catalyzed Stereoselective Defluorosilylation of gem-Difluoroalkenes for the Synthesis of Tetrasubstituted Monofluorinated Vinylsilanes.” Organic Letters, vol. 25, no. 13, Mar. 2023, pp. 2333-2337. https://pubs.acs.org/doi/10.1021/acs.orglett.3c00718.
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