Electrochemical Decarboxylative Silylation of α,β-Unsaturated Carboxylic Acids
Publication type: Journal Article
Publication date: 2023-06-14
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
37314148
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An electrochemical method for the decarboxylative silylation of α,β-unsaturated carboxylic acids was developed. A variety of alkenylsilanes could be obtained in satisfactory yields and excellent selectivities under external oxidant- and metal-free conditions. Mechanistic studies showed that the formation of the silyl radical was mediated by NHPI, which produces the hydrogen atom transfer (HAT) reagent phthalimide N-oxyl (PINO) via multiple-site concerted proton-electron transfer (MS-CPET).
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15
Total citations:
15
Citations from 2024:
15
(100%)
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GOST
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Chen X. et al. Electrochemical Decarboxylative Silylation of α,β-Unsaturated Carboxylic Acids // Organic Letters. 2023. Vol. 25. No. 24. pp. 4562-4566.
GOST all authors (up to 50)
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Chen X., Huang Y., Zhong W. Q., Zhong W., Huang J. Electrochemical Decarboxylative Silylation of α,β-Unsaturated Carboxylic Acids // Organic Letters. 2023. Vol. 25. No. 24. pp. 4562-4566.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.3c01592
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c01592
TI - Electrochemical Decarboxylative Silylation of α,β-Unsaturated Carboxylic Acids
T2 - Organic Letters
AU - Chen, Xinyu
AU - Huang, Yi-Guo
AU - Zhong, Wei Qiang
AU - Zhong, Weiqiang
AU - Huang, Jingmei
PY - 2023
DA - 2023/06/14
PB - American Chemical Society (ACS)
SP - 4562-4566
IS - 24
VL - 25
PMID - 37314148
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2023_Chen,
author = {Xinyu Chen and Yi-Guo Huang and Wei Qiang Zhong and Weiqiang Zhong and Jingmei Huang},
title = {Electrochemical Decarboxylative Silylation of α,β-Unsaturated Carboxylic Acids},
journal = {Organic Letters},
year = {2023},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c01592},
number = {24},
pages = {4562--4566},
doi = {10.1021/acs.orglett.3c01592}
}
Cite this
MLA
Copy
Chen, Xinyu, et al. “Electrochemical Decarboxylative Silylation of α,β-Unsaturated Carboxylic Acids.” Organic Letters, vol. 25, no. 24, Jun. 2023, pp. 4562-4566. https://pubs.acs.org/doi/10.1021/acs.orglett.3c01592.