Palladium-Catalyzed Allylation of P(O)H Compounds: Access to 2-Fluoroallylic Phosphorus Compounds
Publication type: Journal Article
Publication date: 2023-07-12
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
37435974
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An efficient palladium-catalyzed 2-fluoroallylation of P(O)H compounds with gem-difluorocyclopropanes is presented. The reaction provides a variety of 2-fluoroallylic phosphorus compounds in good yields with high Z selectivity through the sequential C-C bond activation, C-F bond cleavage, and C-P coupling process. Various H-phosphonates, H-phosphinates, and secondary phosphine oxides are all tolerated. In addition, the gram-scale synthesis and the late-stage modification of complex bioactive molecules show practical utilities of the transformation.
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26
Total citations:
26
Citations from 2025:
11
(42.31%)
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GOST
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Sun J. et al. Palladium-Catalyzed Allylation of P(O)H Compounds: Access to 2-Fluoroallylic Phosphorus Compounds // Organic Letters. 2023. Vol. 25. No. 28. pp. 5220-5225.
GOST all authors (up to 50)
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Sun J., Ye H., Sun F., Pan Y., Zhu X., Wu X. X. Palladium-Catalyzed Allylation of P(O)H Compounds: Access to 2-Fluoroallylic Phosphorus Compounds // Organic Letters. 2023. Vol. 25. No. 28. pp. 5220-5225.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.3c01674
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c01674
TI - Palladium-Catalyzed Allylation of P(O)H Compounds: Access to 2-Fluoroallylic Phosphorus Compounds
T2 - Organic Letters
AU - Sun, Jie
AU - Ye, Hao
AU - Sun, Fei
AU - Pan, Yi-Yun
AU - Zhu, Xi-Wei
AU - Wu, Xin Xing
PY - 2023
DA - 2023/07/12
PB - American Chemical Society (ACS)
SP - 5220-5225
IS - 28
VL - 25
PMID - 37435974
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2023_Sun,
author = {Jie Sun and Hao Ye and Fei Sun and Yi-Yun Pan and Xi-Wei Zhu and Xin Xing Wu},
title = {Palladium-Catalyzed Allylation of P(O)H Compounds: Access to 2-Fluoroallylic Phosphorus Compounds},
journal = {Organic Letters},
year = {2023},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c01674},
number = {28},
pages = {5220--5225},
doi = {10.1021/acs.orglett.3c01674}
}
Cite this
MLA
Copy
Sun, Jie, et al. “Palladium-Catalyzed Allylation of P(O)H Compounds: Access to 2-Fluoroallylic Phosphorus Compounds.” Organic Letters, vol. 25, no. 28, Jul. 2023, pp. 5220-5225. https://pubs.acs.org/doi/10.1021/acs.orglett.3c01674.