Substituent-Determined Intramolecular Hydrogen Transfer for Photopromoted Intermolecular Cycloaddition of Anthraquinones with Aryl Olefins
Тип публикации: Journal Article
Дата публикации: 2023-11-13
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SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
37955848
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
The formation of intramolecular hydrogen bonds in anthraquinones makes them inert to photoinduced reactions; therefore, it is a great challenge to phototransform these compounds. Herein, we reported a formal visible-light-induced [4 + 2] cycloaddition of both 1-hydroxyanthraquinones and 1-aminoanthraquinones with olefins under external photocatalyst-free conditions with high regioselectivity. More than 60 substrates are disclosed, demonstrating the reliability of this protocol to construct diverse functionalized anthraquinone derivatives.
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Yang F. et al. Substituent-Determined Intramolecular Hydrogen Transfer for Photopromoted Intermolecular Cycloaddition of Anthraquinones with Aryl Olefins // Organic Letters. 2023. Vol. 25. No. 46. pp. 8308-8313.
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Yang F., Lin P., Xu B., Gao Y., Su W. Substituent-Determined Intramolecular Hydrogen Transfer for Photopromoted Intermolecular Cycloaddition of Anthraquinones with Aryl Olefins // Organic Letters. 2023. Vol. 25. No. 46. pp. 8308-8313.
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TY - JOUR
DO - 10.1021/acs.orglett.3c03354
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c03354
TI - Substituent-Determined Intramolecular Hydrogen Transfer for Photopromoted Intermolecular Cycloaddition of Anthraquinones with Aryl Olefins
T2 - Organic Letters
AU - Yang, Fanyuanhang
AU - Lin, Ping
AU - Xu, Biping
AU - Gao, Yuzhen
AU - Su, Weiping
PY - 2023
DA - 2023/11/13
PB - American Chemical Society (ACS)
SP - 8308-8313
IS - 46
VL - 25
PMID - 37955848
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2023_Yang,
author = {Fanyuanhang Yang and Ping Lin and Biping Xu and Yuzhen Gao and Weiping Su},
title = {Substituent-Determined Intramolecular Hydrogen Transfer for Photopromoted Intermolecular Cycloaddition of Anthraquinones with Aryl Olefins},
journal = {Organic Letters},
year = {2023},
volume = {25},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c03354},
number = {46},
pages = {8308--8313},
doi = {10.1021/acs.orglett.3c03354}
}
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Yang, Fanyuanhang, et al. “Substituent-Determined Intramolecular Hydrogen Transfer for Photopromoted Intermolecular Cycloaddition of Anthraquinones with Aryl Olefins.” Organic Letters, vol. 25, no. 46, Nov. 2023, pp. 8308-8313. https://pubs.acs.org/doi/10.1021/acs.orglett.3c03354.