Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle
Publication type: Journal Article
Publication date: 2023-12-28
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
38153981
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Bambus[6]urils and biotin[6]urils are macrocycles with an exceptional affinity for inorganic anions. Here, we investigated statistical condensation of 2,4-dibenzylglycoluril and d-biotin, monomers of the corresponding macrocycles, to prepare the enantiomerically pure macrocycle 1 containing a single d-biotin and five glycoluril units. Host–guest properties of 1 in chloroform solution and solid state were investigated. The macrocycle 1 bearing a single functional group was employed in the formation of [1]rotaxane utilizing reversible covalent bonds.
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Del Mauro A. et al. Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle // Organic Letters. 2023. Vol. 26. No. 1. pp. 106-109.
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Del Mauro A., Lapešová J., Rando C., Šindelář V., Sindelar V. Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle // Organic Letters. 2023. Vol. 26. No. 1. pp. 106-109.
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TY - JOUR
DO - 10.1021/acs.orglett.3c03715
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c03715
TI - Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle
T2 - Organic Letters
AU - Del Mauro, Arico
AU - Lapešová, Jana
AU - Rando, Carola
AU - Šindelář, Vladimír
AU - Sindelar, V
PY - 2023
DA - 2023/12/28
PB - American Chemical Society (ACS)
SP - 106-109
IS - 1
VL - 26
PMID - 38153981
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2023_Del Mauro,
author = {Arico Del Mauro and Jana Lapešová and Carola Rando and Vladimír Šindelář and V Sindelar},
title = {Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle},
journal = {Organic Letters},
year = {2023},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c03715},
number = {1},
pages = {106--109},
doi = {10.1021/acs.orglett.3c03715}
}
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Del Mauro, Arico, et al. “Merging Bambus[6]uril and Biotin[6]uril into an Enantiomerically Pure Monofunctionalized Hybrid Macrocycle.” Organic Letters, vol. 26, no. 1, Dec. 2023, pp. 106-109. https://pubs.acs.org/doi/10.1021/acs.orglett.3c03715.