Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell
Oleg V Bityukov
1, 2
,
O V Bityukov
1, 2
,
Ksenia V. Skokova
1, 2
,
Vera A. Vil’
1, 2
,
Gennady I Nikishin
1
,
Publication type: Journal Article
Publication date: 2023-12-28
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
38153332
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The generation of peroxy radicals from hydroperoxides with subsequent selective peroxidation of 1,3-dicarbonyls in an undivided electrochemical cell under constant current conditions is reported. The method provides a variety of peroxy-containing barbituric acids and 4-hydroxy-2(5H)-furanones with yields of up to 74%. Only the combination of anodic and cathodic processes provides efficient peroxidation by generating a set of alkoxy and peroxy radicals. NaNO3 acts as both an electrolyte and a redox mediator of radical reactions.
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Total citations:
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Citations from 2024:
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Bityukov O. V. et al. Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell // Organic Letters. 2023. Vol. 26. No. 1. pp. 166-171.
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Bityukov O. V., Bityukov O. V., Skokova K. V., Vil’ V. A., Nikishin G. I., Terent'ev A. O. Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell // Organic Letters. 2023. Vol. 26. No. 1. pp. 166-171.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.3c03780
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c03780
TI - Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell
T2 - Organic Letters
AU - Bityukov, Oleg V
AU - Bityukov, O V
AU - Skokova, Ksenia V.
AU - Vil’, Vera A.
AU - Nikishin, Gennady I
AU - Terent'ev, Alexander O.
PY - 2023
DA - 2023/12/28
PB - American Chemical Society (ACS)
SP - 166-171
IS - 1
VL - 26
PMID - 38153332
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (up to 50 authors)
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@article{2023_Bityukov,
author = {Oleg V Bityukov and O V Bityukov and Ksenia V. Skokova and Vera A. Vil’ and Gennady I Nikishin and Alexander O. Terent'ev},
title = {Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell},
journal = {Organic Letters},
year = {2023},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c03780},
number = {1},
pages = {166--171},
doi = {10.1021/acs.orglett.3c03780}
}
Cite this
MLA
Copy
Bityukov, Oleg V., et al. “Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell.” Organic Letters, vol. 26, no. 1, Dec. 2023, pp. 166-171. https://pubs.acs.org/doi/10.1021/acs.orglett.3c03780.