том 26 издание 1 страницы 166-171

Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell

Тип публикацииJournal Article
Дата публикации2023-12-28
scimago Q1
wos Q1
БС1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
The generation of peroxy radicals from hydroperoxides with subsequent selective peroxidation of 1,3-dicarbonyls in an undivided electrochemical cell under constant current conditions is reported. The method provides a variety of peroxy-containing barbituric acids and 4-hydroxy-2(5H)-furanones with yields of up to 74%. Only the combination of anodic and cathodic processes provides efficient peroxidation by generating a set of alkoxy and peroxy radicals. NaNO3 acts as both an electrolyte and a redox mediator of radical reactions.
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ГОСТ |
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Bityukov O. V. et al. Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell // Organic Letters. 2023. Vol. 26. No. 1. pp. 166-171.
ГОСТ со всеми авторами (до 50) Скопировать
Bityukov O. V., Skokova K. V., Vil’ V. A., Nikishin G. I., Terent'ev A. O. Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell // Organic Letters. 2023. Vol. 26. No. 1. pp. 166-171.
RIS |
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TY - JOUR
DO - 10.1021/acs.orglett.3c03780
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c03780
TI - Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell
T2 - Organic Letters
AU - Bityukov, Oleg V
AU - Skokova, Ksenia V.
AU - Vil’, Vera A.
AU - Nikishin, Gennady I
AU - Terent'ev, Alexander O.
PY - 2023
DA - 2023/12/28
PB - American Chemical Society (ACS)
SP - 166-171
IS - 1
VL - 26
PMID - 38153332
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
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@article{2023_Bityukov,
author = {Oleg V Bityukov and Ksenia V. Skokova and Vera A. Vil’ and Gennady I Nikishin and Alexander O. Terent'ev},
title = {Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell},
journal = {Organic Letters},
year = {2023},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c03780},
number = {1},
pages = {166--171},
doi = {10.1021/acs.orglett.3c03780}
}
MLA
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Bityukov, Oleg V., et al. “Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell.” Organic Letters, vol. 26, no. 1, Dec. 2023, pp. 166-171. https://pubs.acs.org/doi/10.1021/acs.orglett.3c03780.