Stereoselective Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Tetrasubstituted gem-Difluoroalkenes
Publication type: Journal Article
Publication date: 2023-12-28
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
38153354
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
We herein describe a diastereoselective Pd(0)-catalyzed Hiyama cross-coupling reaction of gem-difluoroalkenes. The use of organosilicon reagents in this reaction is advantageous over other organometallic reagents by allowing the introduction of a wide range of functional groups, including challenging alkyl groups. Also conveniently, the additive TBAF was not required for (hetero)aryl-substituted difluoroalkenes.
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16
Total citations:
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Citations from 2024:
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(100%)
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GOST
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Li M., Minteer S., Tsui G. C. Stereoselective Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Tetrasubstituted gem-Difluoroalkenes // Organic Letters. 2023. Vol. 26. No. 1. pp. 376-379.
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Li M., Minteer S., Tsui G. C. Stereoselective Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Tetrasubstituted gem-Difluoroalkenes // Organic Letters. 2023. Vol. 26. No. 1. pp. 376-379.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.3c04037
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.3c04037
TI - Stereoselective Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Tetrasubstituted gem-Difluoroalkenes
T2 - Organic Letters
AU - Li, Min
AU - Minteer, Shelley
AU - Tsui, Gavin Chit
PY - 2023
DA - 2023/12/28
PB - American Chemical Society (ACS)
SP - 376-379
IS - 1
VL - 26
PMID - 38153354
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2023_Li,
author = {Min Li and Shelley Minteer and Gavin Chit Tsui},
title = {Stereoselective Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Tetrasubstituted gem-Difluoroalkenes},
journal = {Organic Letters},
year = {2023},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.3c04037},
number = {1},
pages = {376--379},
doi = {10.1021/acs.orglett.3c04037}
}
Cite this
MLA
Copy
Li, Min, et al. “Stereoselective Palladium-Catalyzed Hiyama Cross-Coupling Reaction of Tetrasubstituted gem-Difluoroalkenes.” Organic Letters, vol. 26, no. 1, Dec. 2023, pp. 376-379. https://pubs.acs.org/doi/10.1021/acs.orglett.3c04037.
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