o-Alkynylaryl 2-Cyanoacrylates: A Synthon for the Construction of Diverse Isoquinolones/Napthyridinones
Publication type: Journal Article
Publication date: 2024-02-07
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
38323799
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
o-Alkynylaryl 2-cyanoacrylates have been disclosed as a new synthon for the regioselective synthesis of isoquinolones and naphthyridinones under mild reaction conditions. The attractive feature of this investigation includes carbon–carbon double bond cleavage under metal-free conditions by an intramolecular SN2 reaction. Incorporating two distinct C–I bonds in the resulting products provides facile opportunity for structural elaboration. The viability of the present protocol was unveiled by postfunctionalization with drug analogues and gram-scale synthesis.
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Muskan, Verma A. o-Alkynylaryl 2-Cyanoacrylates: A Synthon for the Construction of Diverse Isoquinolones/Napthyridinones // Organic Letters. 2024. Vol. 26. No. 6. pp. 1238-1242.
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Muskan, Verma A. o-Alkynylaryl 2-Cyanoacrylates: A Synthon for the Construction of Diverse Isoquinolones/Napthyridinones // Organic Letters. 2024. Vol. 26. No. 6. pp. 1238-1242.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.4c00053
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.4c00053
TI - o-Alkynylaryl 2-Cyanoacrylates: A Synthon for the Construction of Diverse Isoquinolones/Napthyridinones
T2 - Organic Letters
AU - Muskan
AU - Verma, Akhilesh
PY - 2024
DA - 2024/02/07
PB - American Chemical Society (ACS)
SP - 1238-1242
IS - 6
VL - 26
PMID - 38323799
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (up to 50 authors)
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@article{2024_Muskan,
author = {Muskan and Akhilesh Verma},
title = {o-Alkynylaryl 2-Cyanoacrylates: A Synthon for the Construction of Diverse Isoquinolones/Napthyridinones},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.4c00053},
number = {6},
pages = {1238--1242},
doi = {10.1021/acs.orglett.4c00053}
}
Cite this
MLA
Copy
Muskan, and Akhilesh Verma. “o-Alkynylaryl 2-Cyanoacrylates: A Synthon for the Construction of Diverse Isoquinolones/Napthyridinones.” Organic Letters, vol. 26, no. 6, Feb. 2024, pp. 1238-1242. https://pubs.acs.org/doi/10.1021/acs.orglett.4c00053.