American Chemical Society (ACS)
Organic Letters
,  том 26 ,  издание 27 ,  страницы 5682-5688

Heteroannulation of Arynes with α-Bromodifluorohydroxamates: An Efficient and General Approach to Access 2,2-Difluoro Indoxyls

Тип публикации: Journal Article
Дата публикации: 2024-06-27
American Chemical Society (ACS)
SCImago Q1
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SJR: 1.007
CiteScore: 7.7
Impact factor: 5
ISSN: 15237060, 15237052
Краткое описание
Herein, we report the first general approach to access N-alkoxy-2,2-difluoro indoxyls, via formal 3 + 2 cycloaddition of aryne and (putative) fluorinated-aza-oxyallyl cation. This transition-metal/oxidant-free transformation occurs under mild reaction conditions with a short reaction time. Mechanistic investigation indicates the possible involvement of the closed form of fluorinated-aza-oxyallyl cation, viz., α-lactam, in the current transformation.
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Deeksha .., Singh R. Heteroannulation of Arynes with α-Bromodifluorohydroxamates: An Efficient and General Approach to Access 2,2-Difluoro Indoxyls // Organic Letters. 2024. Vol. 26. No. 27. pp. 5682-5688.
ГОСТ со всеми авторами (до 50) Скопировать
Deeksha .., Singh R. Heteroannulation of Arynes with α-Bromodifluorohydroxamates: An Efficient and General Approach to Access 2,2-Difluoro Indoxyls // Organic Letters. 2024. Vol. 26. No. 27. pp. 5682-5688.
RIS |
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TY - JOUR
DO - 10.1021/acs.orglett.4c01720
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.4c01720
TI - Heteroannulation of Arynes with α-Bromodifluorohydroxamates: An Efficient and General Approach to Access 2,2-Difluoro Indoxyls
T2 - Organic Letters
AU - Deeksha, .
AU - Singh, Ritesh
PY - 2024
DA - 2024/06/27
PB - American Chemical Society (ACS)
SP - 5682-5688
IS - 27
VL - 26
PMID - 38934600
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
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@article{2024_Deeksha,
author = {. Deeksha and Ritesh Singh},
title = {Heteroannulation of Arynes with α-Bromodifluorohydroxamates: An Efficient and General Approach to Access 2,2-Difluoro Indoxyls},
journal = {Organic Letters},
year = {2024},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.4c01720},
number = {27},
pages = {5682--5688},
doi = {10.1021/acs.orglett.4c01720}
}
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Deeksha, .., and Ritesh Singh. “Heteroannulation of Arynes with α-Bromodifluorohydroxamates: An Efficient and General Approach to Access 2,2-Difluoro Indoxyls.” Organic Letters, vol. 26, no. 27, Jun. 2024, pp. 5682-5688. https://pubs.acs.org/doi/10.1021/acs.orglett.4c01720.
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