volume 17 issue 14 pages 3502-3505

Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles

Publication typeJournal Article
Publication date2015-07-02
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Facile gold-catalyzed heterocyclization based upon intermolecular trapping of the generated α-oxo gold carbenes with various cyanamides R(2)R(3)NCN (R(2)/R(3) = Alk/Alk, -(CH2)2O(CH2)2-, Ar/Ar, Ar/H) has been developed. In most cases, 2-amino-1,3-oxazoles functionalized at the nitrogen atom as well as at the fifth position of the heterocyclic ring (12 examples) were isolated in good to moderate yields.
Found 
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Rassadin V. A., Boyarskiy V. P., Kukushkin V. Y. Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles // Organic Letters. 2015. Vol. 17. No. 14. pp. 3502-3505.
GOST all authors (up to 50) Copy
Rassadin V. A., Boyarskiy V. P., Kukushkin V. Y. Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles // Organic Letters. 2015. Vol. 17. No. 14. pp. 3502-3505.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.5b01592
UR - https://doi.org/10.1021/acs.orglett.5b01592
TI - Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles
T2 - Organic Letters
AU - Rassadin, Valentin A
AU - Boyarskiy, Vadim P
AU - Kukushkin, Vadim Yu.
PY - 2015
DA - 2015/07/02
PB - American Chemical Society (ACS)
SP - 3502-3505
IS - 14
VL - 17
PMID - 26135038
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Rassadin,
author = {Valentin A Rassadin and Vadim P Boyarskiy and Vadim Yu. Kukushkin},
title = {Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles},
journal = {Organic Letters},
year = {2015},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.orglett.5b01592},
number = {14},
pages = {3502--3505},
doi = {10.1021/acs.orglett.5b01592}
}
MLA
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MLA Copy
Rassadin, Valentin A., et al. “Facile Gold-Catalyzed Heterocyclization of Terminal Alkynes and Cyanamides Leading to Substituted 2-Amino-1,3-Oxazoles.” Organic Letters, vol. 17, no. 14, Jul. 2015, pp. 3502-3505. https://doi.org/10.1021/acs.orglett.5b01592.