Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles
Publication type: Journal Article
Publication date: 2015-11-20
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
26588048
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Pyridazine N-oxides are used for the first time as precursors of metallocarbenes. These nitrogen-rich heterocycles led to the discovery of a novel acceptor and donor-acceptor enalcarbenoids. The synthetic utility of these metallocarbenes was demonstrated in the rhodium-catalyzed denitrogenative transannulation of pyridazine N-oxides with pyrroles to the valuable alkyl, 7-aryl, and 7-styryl indoles. The transannulation strategy was applied to the synthesis of a potent anticancer agent.
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42
Total citations:
42
Citations from 2024:
4
(9.52%)
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GOST
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Kanchupalli V., Joseph D., Katukojvala S. Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles // Organic Letters. 2015. Vol. 17. No. 23. pp. 5878-5881.
GOST all authors (up to 50)
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Kanchupalli V., Joseph D., Katukojvala S. Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles // Organic Letters. 2015. Vol. 17. No. 23. pp. 5878-5881.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.5b03064
UR - https://doi.org/10.1021/acs.orglett.5b03064
TI - Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles
T2 - Organic Letters
AU - Kanchupalli, Vinaykumar
AU - Joseph, Desna
AU - Katukojvala, Sreenivas
PY - 2015
DA - 2015/11/20
PB - American Chemical Society (ACS)
SP - 5878-5881
IS - 23
VL - 17
PMID - 26588048
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Kanchupalli,
author = {Vinaykumar Kanchupalli and Desna Joseph and Sreenivas Katukojvala},
title = {Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles},
journal = {Organic Letters},
year = {2015},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.orglett.5b03064},
number = {23},
pages = {5878--5881},
doi = {10.1021/acs.orglett.5b03064}
}
Cite this
MLA
Copy
Kanchupalli, Vinaykumar, et al. “Pyridazine N-Oxides as Precursors of Metallocarbenes: Rhodium-Catalyzed Transannulation with Pyrroles.” Organic Letters, vol. 17, no. 23, Nov. 2015, pp. 5878-5881. https://doi.org/10.1021/acs.orglett.5b03064.